Improving flame-retardant efficiency by incorporation of fullerene in styrene–butadiene–styrene block copolymer/aluminum hydroxide composites

Zhou, Xinrui; Ran, Shiya; Hu, Hefeng; Fang, Zhengping

doi:10.1007/s10973-016-5354-5

Cited by 20 publications

(10 citation statements)

References 30 publications

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“…When 3 wt% fullerene and 53 wt% aluminum hydroxide were added, the composite reached the V-0 grade. A good synergistic effect of the flame retardant was formed [97].…”

Section: Fullerene and Other Nanocarbonsmentioning

confidence: 97%

Nanocarbon-Based Flame Retardant Polymer Nanocomposites

et al. 2021

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In recent years, nanocarbon materials have attracted the interest of researchers due to their excellent properties. Nanocarbon-based flame retardant polymer composites have enhanced thermal stability and mechanical properties compared with traditional flame retardant composites. In this article, the unique structural features of nanocarbon-based materials and their use in flame retardant polymeric materials are initially introduced. Afterwards, the flame retardant mechanism of nanocarbon materials is described. The main discussions include material components such as graphene, carbon nanotubes, fullerene (in preparing resins), elastomers, plastics, foams, fabrics, and film–matrix materials. Furthermore, the flame retardant properties of carbon nanomaterials and their modified products are summarized. Carbon nanomaterials not only play the role of a flame retardant in composites, but also play an important role in many aspects such as mechanical reinforcement. Finally, the opportunities and challenges for future development of carbon nanomaterials in flame-retardant polymeric materials are briefly discussed.

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“…When 3 wt% fullerene and 53 wt% aluminum hydroxide were added, the composite reached the V-0 grade. A good synergistic effect of the flame retardant was formed [97].…”

Section: Fullerene and Other Nanocarbonsmentioning

confidence: 97%

Nanocarbon-Based Flame Retardant Polymer Nanocomposites

et al. 2021

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“…A very high loading content is required to achieve satisfactory flame‐retardant property, which leads to deterioration in the mechanical properties. Cooperated with C 60 , the total loading content of the flame retardant can reduce significantly . In SBS/ATH/C 60 system, the total content of the flame retardant (56 mass%) was lower than that in SBS/ATH system (60mass%) when UL‐94 reached V‐0 level.…”

Section: The Cooperation Effect Of C60 With Other Flame Retardantsmentioning

confidence: 98%

Influence of fullerenes on the thermal and flame‐retardant properties of polymeric materials

Pan

Guo

Ran

et al. 2019

J of Applied Polymer Sci

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At present, the application of fullerene in polymer materials has become an attractive issue. Fullerene can enhance the thermal and flame-retardant properties of polymers due to its high capacity to trap free radicals. Fullerene also has good synergistic effect with inorganic metal flame retardant, intumescent flame retardant, brominated flame retardant (BFR), clay, carbon nanotubes, graphene oxide, and so on. In this review, the impact and mechanism of fullerene and its derivatives on the thermal and flame-retardant properties of polymeric materials are discussed. And the prospect of fullerene in flame-retardant polymer composites is also briefly introduced by analyzing the research progress in the recent years. Scheme 8. Schematic representation of the mechanism for the thermal degradation of HDPE/C 60 composite: (a) the thermal degradation process of HDPE; (b) the thermal degradation process of HDPE/C 60 composite. 53 [Color figure can be viewed at wileyonlinelibrary.com] REVIEW WILEYONLINELIBRARY.COM/APP

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“…Moreover, nano flame retardants are superior to almost all current flame retardants in terms of improving the physical properties of polymer substrates. Since montmorillonite (MMT) nanoparticles were used to fabricate a flame-retarding PA6 nanocomposite by Toyota Corporation (Japan) in 1976, more and more nano flame retardants have been introduced to prepare high-performance flame-retarding polymers [73], such as graphite oxide (GO) [74,75], layered doubled hydroxides (LDH) [76], carbon nanotubes (CNTs) [77], polyhedral oligosilsesquioxane (POSS) [78], fullerene (C60) [79], etc. The flame-retardant mechanisms of nano flame retardants are very complicated, in which the interaction between nano flame retardant and substrate is the critical factor, thus, the flame-retardant mechanism for different nano flame retardants in different polymers may be different due to various structural features of the polymer matrix and nanoparticles.…”

Section: Nano Flame Retardantsmentioning

confidence: 99%

Flame Retardation of Natural Rubber: Strategy and Recent Progress

et al. 2020

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Natural rubber (NR) as a kind of commercial polymer or engineering elastomer is widely used in tires, dampers, suspension elements, etc., because of its unique overall performance. For some NR products, their work environment is extremely harsh, facing a serious fire safety challenge. Accordingly, it is important and necessary to endow NR with flame retardancy via different strategies. Until now, different methods have been used to improve the flame retardancy of NR, mainly including intrinsic flame retardation through the incorporation of some flame-retarding units into polymer chains and additive-type flame retardation via adding some halogen or halogen-free flame retardants into NR matrix. For them, the synergistic flame-retarding action is usually applied to simultaneously enhance flame retardancy and mechanical properties, in which some synergistic flame retardants such as organo-montmorillonite (OMMT), carbon materials, halloysite nanotube (HNT), etc., are utilized to achieve the above-mentioned aim. The used flame-retarding units in polymer chains for intrinsic flame retardation mainly include phosphorus-containing small molecules, an unsaturated chemical bonds-containing structure, a cross-linking structure, etc.; flame retardants in additive-type flame retardation contain organic and inorganic flame retardants, such as magnesium hydroxide, aluminum hydroxide, ammonium polyphosphate, and so on. Concerning the flame retardation of NR, great progress has been made in the past work. To achieve the comprehensive understanding for the strategy and recent progress in the flame retardation of NR, we thoroughly analyze and discuss the past and current flame-retardant strategies and the obtained progress in the flame-retarding NR field in this review, and a brief prospect for the flame retardation of NR is also presented.

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Improving flame-retardant efficiency by incorporation of fullerene in styrene–butadiene–styrene block copolymer/aluminum hydroxide composites

Cited by 20 publications

References 30 publications

Nanocarbon-Based Flame Retardant Polymer Nanocomposites

Nanocarbon-Based Flame Retardant Polymer Nanocomposites

Influence of fullerenes on the thermal and flame‐retardant properties of polymeric materials

Flame Retardation of Natural Rubber: Strategy and Recent Progress

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