Improvement of wear behaviour of titanium by boriding

Abstract

Purpose The purpose of this paper is to achieve a hard and protective borided layer on commercially pure Ti (grade-2) by applying boriding, and to investigate the changes in its microstructure, hardness, friction and wear behaviors. Design/methodology/approach Pack boriding technique was used to form a hard boron diffusion layer on titanium substrate. A powder mixture of amorphous boron and anhydrous borax was used as a solid-state boriding media, and then the boriding was carried out under inert atmosphere. Findings A thick dual boride layer consisting of a monolithic titanium diboride (TiB2) on the top and titanium monoboride (TiB) whiskers beneath that layer formed at relatively low diffusion temperature under pressured inert argon atmosphere in a boriding media containing boron source and activator. With boriding at specified conditions, very hard (4100 Hv0.01) and thick monolithic TiB2 layer formed on the top-most layer which is required for improved tribological applications. Hardness decreased gradually through the TiB whisker layer and finally reached to the hardness of base material. Originality/value This paper investigates the effects of components of boriding mixture and conditions of thermal treatment on the formation of borided layer and its properties. In previous studies, boriding mixtures containing a boron source, an activator and a filler material was generally used at high temperatures around or above 1,050°C to achieve a thick monolithic layer on the top of the surface of titanium. In the present study, no filler material was used to accelerate the boron diffusion because filler materials may inhibit the diffusion of boron atom through the surface of substrate of titanium. Also, diffusion treatment was carried out under pressurized argon atmosphere at relatively low diffusion temperature to achieve boride layer with the improved hardness and durability.

Improvement of Mechanical, Tribological, and Fricative Reduction Properties of Pure Titanium by Boriding

“…It resulted that the surface of the base sample formed a thick and dense layer of TiB 2 . Similar results have been reported in previous studies [14]. TiB 2 was the dominant phase for the samples treated at all boriding temperatures.…”

“…Kara et al reported that boriding titanium at 950 • C substantially increases its wear resistance. Additionally, at this processing temperature, surface hardness achieved the maximum value [14]. Duan Y. H. et al reported the growth kinetics of Ti-6Al-4V alloy by boriding.…”

“…Many preliminary studies of boriding pure Ti have been performed, but few investigated different boriding temperatures [14][15][16][17][18]. Kara et al reported that boriding titanium at 950 • C substantially increases its wear resistance.…”

Tribological investigations of boride layers on Ti6Al4V at room and elevated temperatures

“…Increasing surface hardness is one of the effective methods to improve wear resistance (Kara et al , 2017). Tian et al (2021) found that the surface hardness of Ti-6Al-4V alloy increased to 1100 HV 0.1 compared with the matrix after carburizing.…”

Production and Characterization of Boride and Carbide Layers on AISI 15B30 Steel

“…In another study, Kara, Purcek and Yanar applied a boride layer on pure titanium (grade-2). The COF decreased by about 21% [10]. Furthermore, due to its simplicity and versatility, it can be made in ferrous and non-ferrous high melting point metallic materials, a process that is commonly used today.…”