Abstract:The self-association model is an effective theoretical method for determining the thermodynamic parameters of immiscible molten binary alloys. However, two important parameters (the ratios of numbers of two atoms in the cluster n and the interchange energy W) in the model had confusing temperature dependences, which prevented the statistical mechanical model from accurately predicting the physical and chemical properties at various temperatures. The ratios of the two atoms in the cluster and the interchange en… Show more
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