Kyoto 606-0/, Japan For the basic study on removal of methyl mercaptan from coffee volatiles, adsorption characteristics on zeolite 5A were evaluated for 6 model components in a coffee aroma-containing gas. They were methyl mercaptan, acetaldehyde and 2;-butanedione as aroma components, and nitrogen, carbon dioxide and water as coexisting gas components. Adsorption isotherms for the above components were measured, and heats of adsorption were calculated from the measured isotherms. From the breakthrough curves for binary mixture, the order of adsorption selectivity was determined as water>acetaldehyde>methyl mercaptan>carbon dioxide>2~-butanedione>nitrogen.The order roughly corresponded to the relative order of heats of adsorption. The results suggest that it is necessary to remove water vapor in the aroma-containing gas before the adsorption process for improving the adsorption efficiency of methyl mercaptan. Partial condensation was calculated for a model component system, and it was found that the condensation operation would be useful for the removal of water vapor from an aroma-containing gas.Keywords: adsorptlon selectivity, coffee aroma, heat of adsorption, methyl mercaptan, zeolite 5A, partial condensation Volatiles orlginating from food materials are widely utilized for quality improvement of food products. In the manufacturing of coffee products, aromatized coffee oil that absorbed the volatiles recovered from roasted and ground coffee is added back to liquid coffee extracts or dry products of the extracts as a method of enhancing coffee aroma. Such methods are described in some patents ( Lubensen et al., 1973; Sledlecki et al., 1977;Katz et al., 1985). However, the desirable smell in coffee is formed by a delicate balance in the composition of volatiles. Such aromatized oils often have a strongly irritating sulfurous odor. It is therefore advisable to remove such a pungent sulfur-llke odor in order to increase consumer acceptability. It is difricult to separate selectively sulfur odor components by means of a distillatlon or condensation process based on the difference in volatility of the compounds.An adsorption process has been proposed for quality improvement of coffee aroma evolved from roasted and ground coffee during the commercial extraction process of soluble coffee (Sakano et al, 1996). Zeolite was selected and examined for this purpose because it has a high adsorption selectivity due to the molecular sieving effect and a strong interaction with polar molecules. As the result ofthe previous study, the adsorption process using an A-type zeolite effectively removed the pungent odor components such as methyl mercaptan identlfied in the coffee aroma-containing gas. Improvement of the coffee aroma was confirmed by sensory evaluation of the deodorized products. Zeolite 5A was most appropriate from the viewpoint of separation efficiency of methyl mercaptan from residual aroma compounds.The information on the adsorption characteristics of components in the aroma-containing gas is essential to devel...