A facile hydrothermal strategy was first proposed to synthesize flower-like Co(OH) 2 hierarchical microspheres. Further physical characterizations revealed that the flower-like Co(OH) 2 microspherical superstructures were self-assembled by one-dimension nanobelts with rich mesopores. Electrochemical performance of the flower-like Co(OH) 2 hierarchical superstructures were investigated by cyclic voltammgoram, galvanostatic charge-discharge and electrochemical impedance spectroscopy in 3 M KOH aqueous electrolyte. Electrochemical data indicated that the flower-like Co(OH) 2 superstructures delivered a specific capacitance of 434 Fg −1 at 10 mA cm −2 (about 1.33 Ag −1 ), and even kept it as high as 365 Fg −1 at about 5.33 Ag −1 . Furthermore, the SC degradation of about 8% after 1,500 continuous charge-discharge cycles at 5.33 Ag −1 demonstrates their good electrochemical stability at large current densities.