“…In order to improve the photocatalytic activity of ZnO, different solutions such as, choosing appropriate synthesis method, preparing composite photocatalyst, and synthesizing noble metals doped ZnO have been applied [15][16][17]. In the case of doping ZnO by noble metals, the dopant can act as a scavenger for photogenerated electrons, which promotes interfacial electron-hole separation in the photocatalytic process and increases photocatalytic activity [15][16][17]. Noble metal nanoparticles, such as Au [18,19], Ag [14,15,20,21] Pt [22,23], and Pd [17,24] have been investigated for doping in terms of the size-dependent optical, catalytic, magnetic, and electronic properties [23].…”
Section: Introductionmentioning
confidence: 99%
“…However, the photocatalytic activity of ZnO is restricted by fast recombination rate of the photogenerated electron-hole pairs [8,[13][14]. In order to improve the photocatalytic activity of ZnO, different solutions such as, choosing appropriate synthesis method, preparing composite photocatalyst, and synthesizing noble metals doped ZnO have been applied [15][16][17]. In the case of doping ZnO by noble metals, the dopant can act as a scavenger for photogenerated electrons, which promotes interfacial electron-hole separation in the photocatalytic process and increases photocatalytic activity [15][16][17].…”
“…In order to improve the photocatalytic activity of ZnO, different solutions such as, choosing appropriate synthesis method, preparing composite photocatalyst, and synthesizing noble metals doped ZnO have been applied [15][16][17]. In the case of doping ZnO by noble metals, the dopant can act as a scavenger for photogenerated electrons, which promotes interfacial electron-hole separation in the photocatalytic process and increases photocatalytic activity [15][16][17]. Noble metal nanoparticles, such as Au [18,19], Ag [14,15,20,21] Pt [22,23], and Pd [17,24] have been investigated for doping in terms of the size-dependent optical, catalytic, magnetic, and electronic properties [23].…”
Section: Introductionmentioning
confidence: 99%
“…However, the photocatalytic activity of ZnO is restricted by fast recombination rate of the photogenerated electron-hole pairs [8,[13][14]. In order to improve the photocatalytic activity of ZnO, different solutions such as, choosing appropriate synthesis method, preparing composite photocatalyst, and synthesizing noble metals doped ZnO have been applied [15][16][17]. In the case of doping ZnO by noble metals, the dopant can act as a scavenger for photogenerated electrons, which promotes interfacial electron-hole separation in the photocatalytic process and increases photocatalytic activity [15][16][17].…”
“…Comparing the spectrum of pure ZnO with those of samples doped with 5 and 10 wt% Cd indicates that the The lattice parameters of ZnO and Cd-ZnO with different concentrations were calculated from the XRD using the following equation [16]. Table 1 shows the calculated lattice parameters of the samples.…”
Section: Sample Characterizationmentioning
confidence: 99%
“…Among the various chemical techniques, sol-gel process is a promising method for the preparation of nanomaterials, because of the notable advantages of high purity, good homogeneity, low-temperature synthetic conditions, low equipment cost, and easily controlled reaction parameters [15,16].…”
In the present study, undoped ZnO and CdZnO nanostructures with different weight ratios of cadmium were synthesized by the sol-gel method. Structural and optical properties were investigated by Fourier transform spectroscopy, UV-Vis spectroscopy, scanning electron microscopy, energy-dispersive analytical X-ray, X-ray diffraction, and photoluminescence spectroscopy methods. Moreover, the direct band gap is calculated by Tauc's approach. Furthermore, photocatalytic activity of all samples has been investigated under UV irradiation in an aqueous medium. Compared with pure ZnO, the band gap of the Cd-ZnO decreases and depends on the content of dopants. In addition, photocatalytic activity improves in the presence of a small amount (5 wt%) of cadmium dopant. Graphical Abstract
“…The effect of different parameters such as catalyst loading, solution pH and dye concentration on photodegradation efficiency were evaluated using ZnO and (ZnO-Pd) N CM [15,16].…”
Zinc oxide -palladium nanocomposite material (ZnO-Pd) N CM was prepared and then characterized by UV-Vis spectroscopy, photoluminescence spectroscopy, X-ray diffraction analysis, energy dispersive X-ray analysis and field emission-scanning electron microscopy. The photocatalytic performance of (ZnO-Pd) N CM was investigated by degradation of Congo red under solar light irradiation. Zinc oxide modified with palladium metal could greatly enhance its photocatalytic activity and effectively degraded by Congo red dye.
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