Abstract:Conventional methods for determining
and monitoring the viscosity
of oils are time-consuming, expensive, and in some instances, technically
unfeasible. These limitations can be avoided using low-field nuclear
magnetic resonance (LF-NMR) relaxometry. However, due to the chemical
dissimilarity of oils and various temperatures these oils are exposed
to, as well as LF-NMR equipment limitations, the commonly used models
fail to perform at a satisfactory level, making them impractical for
use in heavy oil and bitume… Show more
“…The transverse relaxation time (T 2 ) provides information about both chemical composition and physicochemical M ac (%) properties of crude oils. [4,[28][29][30] Oils with small T 2 values have a pronounced spin-spin interaction, suggesting a higher viscosity, which in turn implies the presence of heavier and long chain chemical compounds. [30,31] In this context, the T 2 values can provide molecular information from crude oils and their distillates.…”
Crude oil distillates are a highly useful industrial product, mainly for energy generation. Unfortunately, they are rarely studied, mainly due to the low accessibility to products directly obtained from the distillation process, which is a laborious, expensive, and time-consuming operation. This work presents and discusses the use of time-domain nuclear magnetic resonance (TD-NMR) as a simple, affordable, and straightforward tool for the development of correlations supported on the transverse relaxation time (T 2 ) and boiling temperature. The results point out a high convergence between TD-NMR experimental data and the ASTM D2892 method for distillates from light, medium, and heavy oils, with up to 52.20% of accumulated mass and boiling point temperature (T b ) up to 400 C. Furthermore, an unprecedented relationship between T 2 values and the accumulated mass of the distillates is first demonstrated. This new insight opens new perspectives for future prediction of accumulated mass for unknown crude oils, placing the TD-NMR relaxometry as an appeal spectroscopy approach with a potential to meaningfully contribute to the daily refining petrochemical industry field operations.
“…The transverse relaxation time (T 2 ) provides information about both chemical composition and physicochemical M ac (%) properties of crude oils. [4,[28][29][30] Oils with small T 2 values have a pronounced spin-spin interaction, suggesting a higher viscosity, which in turn implies the presence of heavier and long chain chemical compounds. [30,31] In this context, the T 2 values can provide molecular information from crude oils and their distillates.…”
Crude oil distillates are a highly useful industrial product, mainly for energy generation. Unfortunately, they are rarely studied, mainly due to the low accessibility to products directly obtained from the distillation process, which is a laborious, expensive, and time-consuming operation. This work presents and discusses the use of time-domain nuclear magnetic resonance (TD-NMR) as a simple, affordable, and straightforward tool for the development of correlations supported on the transverse relaxation time (T 2 ) and boiling temperature. The results point out a high convergence between TD-NMR experimental data and the ASTM D2892 method for distillates from light, medium, and heavy oils, with up to 52.20% of accumulated mass and boiling point temperature (T b ) up to 400 C. Furthermore, an unprecedented relationship between T 2 values and the accumulated mass of the distillates is first demonstrated. This new insight opens new perspectives for future prediction of accumulated mass for unknown crude oils, placing the TD-NMR relaxometry as an appeal spectroscopy approach with a potential to meaningfully contribute to the daily refining petrochemical industry field operations.
“…In the data processing phase, for known leak events, the level of the leak is annotated in the corresponding data segments to serve as a reference for model training. 213 The process of establishing and training the model for leak prediction is similar to that for leak localization. Finally, this trained model is used to predict the level of leaks.…”
Section: Sensor Fusion and Multimodal Leakage Diagnosismentioning
confidence: 99%
“…Alternatively, the leak level can be predicted based on the concentration of diffused hydrogen, in conjunction with data such as pressure and temperature from relevant equipment. In the data processing phase, for known leak events, the level of the leak is annotated in the corresponding data segments to serve as a reference for model training . The process of establishing and training the model for leak prediction is similar to that for leak localization.…”
As fuel cell vehicles (FCVs) are increasingly put on
the market
and hydrogen refueling stations (HRSs) are built accordingly, fatal
accidents caused by explosion due to hydrogen leakage are reported
and have become a critical issue. The explosion results from complicated
processes associated with the so-called hydrogen jet and diffusion
when the hydrogen leaks from FCVs or HRSs, demonstrating its sophisticated
characteristics and presenting significant technical challenges. Recently,
particularly in the past a few years, researchers have established
a variety of theoretical models to reveal the relevant mechanisms
and introduced a series of monitoring/diagnostic approaches to detect
and control the relevant hazards. This comprehensive review summarizes
the major research outcomes and particularly the state-of-the-art
progresses in relation to hydrogen leakage in FCVs and HRSs, including
(1) subsonic jets, (2) underexpanded jets, (3) hydrogen diffusion
behavior, (4) hazard reduction methods for confined and free spaces,
(5) four types of widely used hydrogen detection technologies, and
(6) the application of hydrogen leakage diagnostic methods in different
systems. An insight of the review is that research on hydrogen leakage
related to FCVs and HRSs should be combined with the relevant realistic
characteristics. The characteristics of hydrogen jets generated in
real gaps are discussed, and hazard reduction methods are proposed
based on the characteristics of hydrogen diffusion in different confined
and free spaces. It is suggested that, in order to integrate and evaluate
multiple sensor data points and more accurately determine the leakage
location and the leakage level, artificial intelligence technologies
could be introduced to resolve the issues encountered currently.
“…To analyze the overall performance of the prediction model, this paper selects root mean square error (RMSE), average absolute error (MAE), and coefficient of determination (R 2 ) to evaluate the above four prediction models [28].…”
Section: Comparison With Other Common Optimization Algorithmsmentioning
The occurrence of debris flows are a significant threat to human lives and property. Estimating the debris flow scale is a crucial parameter for assessing disaster losses in such events. Currently, the commonly used method for estimating debris flow runoff relies on fitting techniques, which often yield low prediction accuracy and limited data representation capabilities. Addressing these challenges, this study proposes an improved grey wolf algorithm optimized support vector machine prediction model. The model’s effectiveness is validated using data from 72 debris flow events in Beichuan County. The results demonstrate a prediction accuracy of 95.9% using this approach, indicating its strong predictive capabilities for debris flow scale. Additionally, it is observed that the basin area, the basin relative, and the main channel length are the key factors influencing debris flow scale in Beichuan County.
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