LaB6 nanofilm is coated on the top surface of silicon nanopillars forming a field emission array (FEA). Such a structure will be referred to subsequently as a “LaB6 hat-coated Si-FEA”. The electron emission mechanism of the LaB6 hat-coated Si-FEA is analyzed by OPERA simulation software. It reveals that the electron emission mainly depends on the LaB6 film edge. Moreover, the LaB6 hat-coated Si-FEA sample is prepared by microsphere lithography, and the field emission properties are tested. The results show that when the anode voltage is 850 V, the field emission current density reaches 458 mA/cm2, which is in good agreement with the simulation results. This work demonstrates that the field emission cathodes with low cost, high integration and high current can be realized by using LaB6 as emitter material combined with microsphere lithography technology.