Background: The nuclear structure of the cluster bands in 20 Ne presents a challenge for many theoretical approaches. It is especially difficult to explain the broad 0 + and 2 + states, both at around 9 MeV excitation energy. More reliable experimental data for these levels is important for proper quantitative assessment and development of theoretical methods.Purpose: To obtain new data on 20 Ne α-cluster structure.Method: Thick target inverse kinematics technique was used to study the 16 O+α resonance elastic scattering and the data were analyzed using an R-matrix approach. The 20 Ne spectrum, the cluster and nucleon spectroscopic factors were calculated using cluster-nucleon configuration interaction model (CNCIM). Conclusions: Our experimental results obtained by the TTIK method generally confirm the adopted data on α cluster levels in 20 Ne. The CNCIM gives a good description of the 20 Ne positive parity states up to an excitation energy of ∼ 7 MeV, predicting reasonably well the excitation energy of the states and their cluster and single particle properties. At higher excitations, a qualitative disagreement with the experimentally observed structure is evident, especially for broad resonances.