2014 IEEE International Electric Vehicle Conference (IEVC) 2014
DOI: 10.1109/ievc.2014.7056095
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Impedance spectroscopy characterisation of automotive NMC/graphite Li-ion cells aged with realistic PHEV load profile

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Cited by 22 publications
(22 citation statements)
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“…This is also in accordance with previous studies that suggest that the loss of lithium and subsequent SEI-growth can be modelled as proportional to the square root of time [16]. The EIS characteristics undergo different changes for the studied cases, but a general trend is that the width of the semi-circle, often described as caused by the charge transfer impedance, is either constant or slightly decreased for most tests, possibly indicating a larger accessible electrode surface area [33].…”
Section: Discussionsupporting
confidence: 76%
“…This is also in accordance with previous studies that suggest that the loss of lithium and subsequent SEI-growth can be modelled as proportional to the square root of time [16]. The EIS characteristics undergo different changes for the studied cases, but a general trend is that the width of the semi-circle, often described as caused by the charge transfer impedance, is either constant or slightly decreased for most tests, possibly indicating a larger accessible electrode surface area [33].…”
Section: Discussionsupporting
confidence: 76%
“…Several models derived of this technique can be found in the literature [74][75][76][77]. Impedance models can be very useful in Li-Ion cell diagnosis.…”
Section: Impedance Modelsmentioning
confidence: 99%
“…The Constant Phase Element (CPE) is a particular equivalent circuit passive element, which improves the match between the fit and the experimental battery EIS measurement in broadband. Usually it is used to describe the electrical properties of double layer capacitors [13] between the battery electrode and the electrolyte [14]. Its transfer function in frequency domain is defined as follows:…”
Section: A Analysis In Frequency-domainmentioning
confidence: 99%
“…Last consideration is the following: usually in the battery the slope of the straight line at the LF is equal to α=0.5. This particular CPE is the so-called Warburg impedance and this is usually used to describe the diffusion of lithium ions in the porous active material of the electrodes [14].…”
Section: A Analysis In Frequency-domainmentioning
confidence: 99%
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