To
understand the risk factors of spontaneous combustion fire during
the storage process of a biomass pile, the effects of various factors
on its self-ignition process under adiabatic oxidation conditions
were investigated. Thermogravimetry, differential scanning calorimetry,
and Fourier transform infrared spectroscopy (FTIR) were used to analyze
the behavior of a series of biomass samples before and after the inhibition.
A total of 12 typical inorganic salts and antioxidants were used as
chemical inhibitors for suppressing the spontaneous combustion of
the lignocellulosic biomass. A steady increase in the heating rate
of the compound can be observed with a decrease in the particle size
from 4.00 to 0.18 mm. Samples with a moisture content of 1% are most
susceptible to spontaneous combustion. Interestingly, the effect of
the ventilation rate on the self-heating properties of the samples
increases when the temperature is higher than 70 °C. In the 40–350
°C range, CaCl2, citric acid, MgCl2, and
Na3PO4 reduce the heat release by 123.32–492.15
J/g. Among these compounds, CaCl2 exhibits the optimal
inhibition effect. According to the FTIR results, the inhibitors mainly
target the −OH, C–O, C–H, and CO groups.
Moreover, the weakening of these active sites by slowing their oxidation
rate is the main responsible for retarding the spontaneous combustion
of the biomass. This work contributes in the development of novel
strategies to shed some light on the spontaneous combustion of biomasses.