Foam
is used in CO2-enhanced oil recovery due to its
potential high benefits in mitigating all three causes of CO2 poor sweep efficiency, as it provides a means to lower the effect
of permeability heterogeneity, overcome viscous instability, and minimize
the occurrence of gravity override. The conventional foaming surfactants
are not suitable in contact with oil due to premature lamellae rupture,
need for copious amounts of water to generate foam, surfactant loss
due to adsorption on the rock or partitioning between water and oil,
and less tolerance against salinity, pressure, and temperature. The
surfactant blending and addition of CO2-philic functionalities
in surfactant structure are suggested to mitigate the above problems,
enhance foam stability, improve mobility control, and accelerate foam
propagation. However, there is a lack of general guidelines on the
evaluation of CO2-philic surfactant properties and applications
and the surfactant structure–performance analysis. In the present
work, tailor-made laboratory tests and simulation analysis were conducted
on CO2-philic surfactants with different structures and
chain lengths in conditions close to a Malaysian reservoir case and
in the presence of oil. The results from experiments combined with
analytical analysis of foam flow parameters are used to provide a
comprehensive simulation model of a CO2-philic surfactant
alternating gas process. A meaningful correlation between the CO2-philic surfactant structure and the sensitivity of foam model
to different parameters was observed. On the basis of sensitivity
analysis results, optimization of CO2-philic surfactant
activity at gas–water and oil–water interfaces can improve
the system recovery through macroscopic and microscopic displacement.