2022
DOI: 10.1016/j.solmat.2022.111648
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Impact of polymeric stabilisers on the reaction kinetics of SrBr2

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Cited by 12 publications
(2 citation statements)
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“…where p ref is equal to 1 bar, ΔS (J mol − 1 K − 1 ) is the standard entropy of dehydration per mole of water and ΔH (kJ mol − 1 ) is the standard enthalpy of dehydration per moles of water. Despite we could have used other more accurate models to reproduce the hydration rate [36,37], based on previous experimental work [4,31,40,43] this is constant almost up to full conversion, therefore also a linear model can effectively provide an estimate for k. The only assumption made at this stage is that powder particles are not porous.…”
Section: The μM-size Scale: Hydration Kinetics Of Salt Powdersmentioning
confidence: 99%
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“…where p ref is equal to 1 bar, ΔS (J mol − 1 K − 1 ) is the standard entropy of dehydration per mole of water and ΔH (kJ mol − 1 ) is the standard enthalpy of dehydration per moles of water. Despite we could have used other more accurate models to reproduce the hydration rate [36,37], based on previous experimental work [4,31,40,43] this is constant almost up to full conversion, therefore also a linear model can effectively provide an estimate for k. The only assumption made at this stage is that powder particles are not porous.…”
Section: The μM-size Scale: Hydration Kinetics Of Salt Powdersmentioning
confidence: 99%
“…In a kinetic measurement, samples were first equilibrated at the conditions at which the lowest hydrate is the only phase present. SrBr 2 ⋅H 2 O was obtained from SrBr 2 ⋅6H 2 O at 60 • C and 1.7 mbar [43]. CaC 2 O 4 was equilibrated at 160 • C and under pure nitrogen flow.…”
Section: Thermogravimetric Analysis (Tga)mentioning
confidence: 99%