Impact of Interfacial Halogen Bonding with a Surfactant on Miniemulsion Reversible Chain Transfer-Catalyzed Polymerization
Masaya Sadakane,
Atsushi Goto,
Atsushi Harada
et al.
Abstract:The application of reversible chain transfer-catalyzed polymerization (RTCP)�a type of reversible deactivation radical polymerization (RDRP)�in aqueous heterogeneous polymerization is important for the direct synthesis of functional polymer particles from monomeric species. In this study, RTCP using tetraiodomethane (CI 4 ) was demonstrated as a catalyst in a miniemulsion system in the presence of different types of surfactants to investigate the effects of surfactant species on polymerization control. We foun… Show more
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