The goal of this
research was to investigate the effects of torrefying
temperature (220, 260, and 300 °C) on the physicochemical properties,
kinetics, thermodynamic parameters, and reaction processes of Acer palmatum (AP) during the pyrolysis process.
The kinetics of raw materials and torrefied biomass were studied by
using three kinetic models, and the main function graph approach was
employed to find the reaction mechanism. The torrefied biomass produced
at temperatures of 220 °C (AP-220), 260 °C (AP-260), and
300 °C (AP-300) was thermogravimetrically analyzed at four different
heating rates (5, 10, 15, and 20 °C/min). In comparison to the
raw material, the average activation energy of torrefied biomass declined
with increasing temperature, from 174.13 to 84.67 kJ/mol (FWO), 172.52
to 81.24 kJ/mol (KAS and DAEM). The volatile contents of AP and AP-220
are higher than those of AP-260 and AP-300, indicating that the random
nucleation model occupies the central position. Compared with the
raw biomass, the average Gibbs free energy (ΔG) of torrefied biomass increased from 157.97 to 195.38 kJ/mol. The
mean enthalpy change (ΔH) during the torrefaction
process is positive, while the mean entropy change (ΔS) of the torrefaction of biomass is negative, decreasing
from 16.93 to −151.53 kJ/mol (FWO) and from 14.36 to −156.06
kJ/mol (KAS and DAEM). Overall, the findings provide a comprehensive
understanding of the kinetics and improved features of torrefied biomass
as a high-quality solid fuel.