Immobilisation of the polyoxometallate cluster, K6NaH[Sb2W20Fe2O70(H2O)6]·29H2O, in a polypyrrole film

Syntheses and Crystal Structures of dmso‐Coordinated Tungstoantimonates(III) and ‐bismuthates(III)

“…The first wave is a one-electron process, assigned to the Ru 3+/2+ couple; the second and third waves are also oneelectron processes, assigned to the Fe 3+/2+ couples, whereas the latter two waves are multi-electron processes attributed to the redox reaction of the tungsten-oxo framework for [18,37] However, the voltammogram of 4a displays four redox waves at +1.11, 0.33, 0.14, and -0.35 V, as shown in Figure 8. The first three redox waves are essentially identical with those of 3a, and the fourth wave is a multi-electron process assigned to the redox reaction of the tungsten-oxo framework for tungstobismuthate (see Supporting Information, Figure S12).…”

Exploring the electronic properties and cation complexation of polyoxoaurates [AuIII4X4Om]n−(X = SiIV, PV, GeIV, AsV, and SeIV) using quantum chemical calculations

“…In this case, the influence of the alkali cations seems to be critical during the synthesis and self-assembly of the nanoclusters. The critical influence of cations on the nanocluster synthesis has been demonstrated both experimentally [18][19][20][21][22][23] and theoretically. 24 One of the mostdeveloped members of these host-guest materials is the uranylperoxide cluster.…”

Ultrasound-Assisted Synthesis of Hybrid Phosphomolybdate–Polybenzidine Containing Silver Nanoparticles for Electrocatalytic Detection of Chlorate, Bromate and Iodate Ions in Aqueous Solutions

“…Besides their manifold properties, conducting organic polymers are able to provide some electrocatalytic reactivity, and therefore, synergistic effects can be anticipated from such hybrids [6,7]. Several methods have been adopted to fabricate such hybrid electrochemical interfaces: Layer-by-layer assembly [8][9][10][11][12][13], electrochemical co-deposition [14], carbon paste [15] and casting [16], wherein polyaniline [6,[16][17][18], polypyrrole [7,19,20], poly(N-methylpyrrole) [21], poly(3-methylthiophene) [17,22], poly(amidoamine) [8], poly (3,4-ethylenedioxythiophene) [23][24][25][26] etc. were employed as organic conducting polymer backbones.…”