(Iminopyridine)Pd (II) complexes as versatile catalysts for copolymerization and terpolymerization of vinyl arene, ethylene, and carbon monoxide

Lee, Seulchan; Chae, Ju-Hyung; Yang, Yongmoon; Lee, In-Hwan; Jang, Hye‐Young

doi:10.1002/aoc.6337

Cited by 3 publications

(2 citation statements)

References 38 publications

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“…Moreover, the thermal properties of the polyketone products could be tuned by the styrene content. [ 195 ]…”

Section: Carbonylation In Alternative Solventsmentioning

confidence: 99%

Recent Advances in Catalytic Carbonylation Reactions in Alternative Reaction Media

Árvai,

Mika

2023

Chin. J. Chem.

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Comprehensive SummarySince the discovery of the hydroformylation (oxo‐synthesis or Roelen reaction) and the Reppe‐reaction, the transition metal‐catalyzed carbonylation reactions, providing versatile, facile, and even atom‐economic methods for the selective incorporation of C=O functionality to various skeletons, have gained tremendous importance in synthetic organic chemistry from laboratories to industrial applications. The carbonylation of carbon‐carbon multiple bonds, aromatic halides, triflates etc. in the presence of various nucleophiles has led the way to produce aldehydes, carboxylic acids, esters, amides, etc. in the fine chemical industry. However, these protocols usually proceed in conventional, fossil‐based, and usually toxic reaction environments. Thus, several attempts have been directed to develop efficient carbonylation methods in alternative, less harmful, non‐fossil‐based and even in renewable reaction media. In this review, we overview the recent applications of alternative solvents such as water, biomass‐based alcohols, γ‐valerolactone (GVL), 2‐methyltetrahydrofuran (2Me‐THF), ionic liquids (ILs), deep eutectic solvents (DES), and alkyl levulinates, limonene, α‐pinene, and dimethyl carbonate as well as fluorous media to improve efficiency, safety and environmentally benign nature of carbonylation protocols.This article is protected by copyright. All rights reserved.

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“…Moreover, the thermal properties of the polyketone products could be tuned by the styrene content. [ 195 ]…”

Section: Carbonylation In Alternative Solventsmentioning

confidence: 99%

Recent Advances in Catalytic Carbonylation Reactions in Alternative Reaction Media

Árvai,

Mika

2023

Chin. J. Chem.

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“…However, the formation of stable acyl radicals during FRP prevents further chain propagation and makes this approach challenging. In the IP of ethylene–CO monomers, palladium(II) catalysts are the most prosperous catalytic systems. − Also, nickel complexes can catalyze the coordination copolymerization of ethylene and carbon monoxide. − …”

Section: Green Chemistry In Functional Polyolefinsmentioning

confidence: 99%

Tailor-Made Functional Polyolefins of Complex Architectures: Recent Advances, Applications, and Prospects

2022

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Polyolefins play a crucial role in the polymer industry because of their low-cost monomers and well-established production processes. Recent years have witnessed tremendous progress in direct and tandem copolymerization strategies that provide an opportunity of developing polyolefins bearing polar groups with distinctive architectures and properties. In this perspective, we first highlight new routes for the proficient synthesis of tailor-made functional polyolefins and briefly discuss their designing tactics. Then, we attempt to categorize these, recently appeared in the literature, innovative functional polyolefins on the basis of their applications. The prospected future applications of polar olefin copolymers include biomedical materials, catalysts, energy storage devices, and conductive polymers, which open up new arenas and paradigms for academic research and industrial products development. Critical issues concerning intelligent functional polyolefins and green chemistry are discussed, too.

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Alternating copolymerization of carbon monoxide and vinyl arenes using [N,N] bidentate palladium catalysts

Cheung

Shi

Pei

et al. 2022

Journal of Polymer Science

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The alternating copolymers of carbon monoxide (CO) and vinyl arene monomers, namely aromatic polyketones, are a family of attractive engineering plastic. In the catalytic synthesis of this kind of polymeric materials, [N,N] bidentate palladium catalysts represent the most successful catalytic systems.In this review, we introduce the present status of polyketone synthesis, with a focus on the aromatic polyketones made from vinyl arene and CO. We also address the palladium-catalyzed CO/vinyl arene alternating copolymerization mechanism. A variety of [N,N] bidentate palladium catalysts bearing 2,2 0bipyridine, 1,10-phenanthroline, α-diimine, and pyridine-imine ligands are surveyed for CO/vinyl arene copolymerization. The effects of vinyl arene monomer, counteranion, and solvent on copolymerization are also discussed.The copolymerization stereochemistry including chain end-control and enantiomorphic site control mechanisms is introduced. This review aims to promote the design of [N,N] bidentate palladium catalysts for CO/vinyl arene copolymerization for the development of high-performance aromatic polyketones.

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(Iminopyridine)Pd (II) complexes as versatile catalysts for copolymerization and terpolymerization of vinyl arene, ethylene, and carbon monoxide

Cited by 3 publications

References 38 publications

Recent Advances in Catalytic Carbonylation Reactions in Alternative Reaction Media

Recent Advances in Catalytic Carbonylation Reactions in Alternative Reaction Media

Tailor-Made Functional Polyolefins of Complex Architectures: Recent Advances, Applications, and Prospects

Alternating copolymerization of carbon monoxide and vinyl arenes using [N,N] bidentate palladium catalysts

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