Bioinorganic Chemistry of Copper 1993
DOI: 10.1007/978-94-011-6875-5_26
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Imidazole-Ligated Copper Complexes: Synthesis, Structure, and Reactivity

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Cited by 3 publications
(3 citation statements)
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“…[5] In general, the electronic structures of pyridinyl, pyrazolyl or imidazolyl complexes differ strongly due to the differences in σ and π donor abilities. [6][7][8][9] severe disorders between pyrazolyl and pyridinyl donor groups are observed such that bis(pyrazolyl) and (pyrazolyl)(pyridinyl) coordination modes are concomitantly found. The donor competition is dissected by DFT calculation of the energy differences between the two coordination modes and NBO analysis of the donor situation.…”
Section: Introductionmentioning
confidence: 99%
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“…[5] In general, the electronic structures of pyridinyl, pyrazolyl or imidazolyl complexes differ strongly due to the differences in σ and π donor abilities. [6][7][8][9] severe disorders between pyrazolyl and pyridinyl donor groups are observed such that bis(pyrazolyl) and (pyrazolyl)(pyridinyl) coordination modes are concomitantly found. The donor competition is dissected by DFT calculation of the energy differences between the two coordination modes and NBO analysis of the donor situation.…”
Section: Introductionmentioning
confidence: 99%
“…With regard to π donor abilities, pyrazolyl is superior to pyridinyl as well 5. In general, the electronic structures of pyridinyl, pyrazolyl or imidazolyl complexes differ strongly due to the differences in σ and π donor abilities 69…”
Section: Introductionmentioning
confidence: 99%
“…Substantial rate accelerations for hydrolysis, particularly of carboxylic acid esters, have been attained with some of these model Cu(II) and Zn(II) complexes (33)(34)(35)(36). Although Cu complexes, which reasonably mimic the structural and spectroscopic features of the Cu-hydroxylases, have been prepared (37)(38)(39)(40), few possess polyimidazole ligands or have been shown to promote the hydroxylation of relevant substrates (usually stoichiometric hydroxylation of their own ligands is a major problem) (41)(42)(43)(44), and none of these reactions are catalytic.…”
mentioning
confidence: 99%