II. Energy Levels of Trivalent Ions in Rare-Earth Oxides

Konstantinov, V. L.; Rogovitch, V. I.; Sapozhnikov, V. A.; Skornyakov, G. F.

doi:10.1080/00387017708067487

Spectroscopy Letters

1977

DOI: 10.1080/00387017708067487

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II. Energy Levels of Trivalent Ions in Rare-Earth Oxides

V. L. Konstantinov

V. I. Rogovitch

V. A. Sapozhnikov

et al.

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Covalency in cubic lanthanide sesquioxides

Angelov¹

1977

J. Phys. C: Solid State Phys.

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The overlap integrals (2s mod 4f), (2p sigma mod 4f), and (2p pi mod 4f) have been calculated for the entire series of cubic lanthanide sesquioxides (C-Ln2O3) through analytical five-term (2s, 2p: O2-) and four-term (4f:Ln3+) ground-state wavefunctions. The set of distances used for C2 and C3i cation sites is reported for the first time. It has been found that only pi -type electron delocalisation is feasible within the fragment Ln3+-O2-; the respective overlap integrals vary from 0.12 to 0.03.

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Covalency in cubic lanthanide sesquioxides

Angelov¹

1977

J. Phys. C: Solid State Phys.

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Nephelauxetic effect and (r^k)_4fexpectation values of Er³⁺in ionic crystals

Angelov¹

1984

J. Phys. C: Solid State Phys.

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II. Energy Levels of Trivalent Ions in Rare-Earth Oxides

Cited by 2 publications

References 2 publications

Covalency in cubic lanthanide sesquioxides

Covalency in cubic lanthanide sesquioxides

Nephelauxetic effect and (r^k)_4fexpectation values of Er³⁺in ionic crystals

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II. Energy Levels of Trivalent Ions in Rare-Earth Oxides

Cited by 2 publications

References 2 publications

Covalency in cubic lanthanide sesquioxides

Covalency in cubic lanthanide sesquioxides

Nephelauxetic effect and (rk)4fexpectation values of Er3+in ionic crystals

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Product

Resources

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Nephelauxetic effect and (r^k)_4fexpectation values of Er³⁺in ionic crystals