Abstract:Studying the structural environment of the VIV ions doped in the metal-organic framework (MOF) DUT-5(Al) ((AlIIIOH)BPDC) with electron paramagnetic resonance (EPR) reveals four different vanadium-related spectral components. The Spin-Hamiltonian parameters...
“…In contrast, the Raman analysis of isoreticular DUT-5 36,37 over time (up to 70 h) under the same ambient conditions revealed the immutability of the DUT-5 structure (Fig. S8†), which makes switchable DUT-4 a potentially important MOF for diverse applications.…”
The threshold structural transformation of DUT-4 metal-organic framework (MOF) from an ordered to distorted phase during exposure at ambient conditions has been revealed by \textit{in situ} X-ray diffraction analysis, Raman...
“…In contrast, the Raman analysis of isoreticular DUT-5 36,37 over time (up to 70 h) under the same ambient conditions revealed the immutability of the DUT-5 structure (Fig. S8†), which makes switchable DUT-4 a potentially important MOF for diverse applications.…”
The threshold structural transformation of DUT-4 metal-organic framework (MOF) from an ordered to distorted phase during exposure at ambient conditions has been revealed by \textit{in situ} X-ray diffraction analysis, Raman...
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