Identification of lead compounds in flames and determination of the PbO bond energy

Friswell, N. J.; Jenkins, D. R.

doi:10.1016/s0010-2180(72)80210-4

Cited by 13 publications

(6 citation statements)

References 7 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The most probable Fl compound, which could be formed during the thermalization process is FlO ( Liu et al, 2001 ). The stability of the metal-oxygen bond in monoxides decreases in the sequence PbO > HgO > FlO ( Friswell and Jenkins, 1972 ; Liu et al, 2001 ; de Macedo et al, 2011 ). Both, Pb 0 and PbO, are low-volatile species and should adsorb on SiO 2 at room temperature ( Lens et al, 2018 ; Yu et al, 2021 ).…”

Section: Resultsmentioning

confidence: 99%

On the adsorption and reactivity of element 114, flerovium

et al. 2022

View full text Add to dashboard Cite

Flerovium (Fl, element 114) is the heaviest element chemically studied so far. To date, its interaction with gold was investigated in two gas-solid chromatography experiments, which reported two different types of interaction, however, each based on the level of a few registered atoms only. Whereas noble-gas-like properties were suggested from the first experiment, the second one pointed at a volatile-metal-like character. Here, we present further experimental data on adsorption studies of Fl on silicon oxide and gold surfaces, accounting for the inhomogeneous nature of the surface, as it was used in the experiment and analyzed as part of the reported studies. We confirm that Fl is highly volatile and the least reactive member of group 14. Our experimental observations suggest that Fl exhibits lower reactivity towards Au than the volatile metal Hg, but higher reactivity than the noble gas Rn.

show abstract

Section: Resultsmentioning

confidence: 99%

On the adsorption and reactivity of element 114, flerovium

et al. 2022

View full text Add to dashboard Cite

show abstract

“…MXm(s/l> ' MXm(g, > M(g) + 7ttX(g) (4) in the heated graphite atomizer. We will use these equations to form our simplified model.…”

Section: Theorymentioning

confidence: 99%

“…The formation of analyte atoms in various flames has been discussed by many workers. As convenient cells for the study of high-temperature reactions, flames have been used to obtain spectroscopic evidence of reaction intermediates and bond dissociation energies of stable species (1)(2)(3)(4)(5)(6)(7)(8)(9)(10). However, little has been reported regarding the atomization processes in graphite furnace atomizers.…”

mentioning

confidence: 99%

See 1 more Smart Citation

Studies on the mechanism of atom formation in graphite furnace atomic absorption spectrometry

Sturgeon¹,

Chakrabarti²,

Langford³

1976

Anal. Chem.

291

129

View full text Add to dashboard Cite

“…4,10 In LSMO-0.11 manganite, the concentration of the defects viz oxygen vacancies is expected to be less than that in ferroelectrics like PZT due to the absence of volatile elements in the former and also the bond dissociation energy being greater. 28,29 This renders in lowering of the pinning field. For example, in typical ferroelectrics (having less defects), such as barium titanate or triglycine sulfate, the values of E 0 are in the range of 500-2000 V/cm.…”

Section: Resultsmentioning

confidence: 99%

Domain growth kinetics in La0.89Sr0.11MnO3 single crystal studied by piezoresponse force microscopy

Panwar

Bdikin

Morozovska

et al. 2012

Journal of Applied Physics

View full text Add to dashboard Cite

Local conductivity and the role of vacancies around twin walls of (001)−BiFeO3 thin films J. Appl. Phys. 112, 052003 (2012) Characterization of local piezoelectric behavior of ferroelectric GeTe and Ge2Sb2Te5 thin films J. Appl. Phys. 112, 052018 (2012) Domain relaxation dynamics in epitaxial BiFeO3 films: Role of surface charges J. Appl. Phys. 112, 052017 (2012) Domain evolution in lead-free thin film piezoelectric ceramics J. Appl. Phys. 112, 052014 (2012) Complex domain structure in relaxed PbTiO3 thick films grown on (100)cSrRuO3//(100)SrTiO3 substrates Ferroelectric-like nanodomains have been written by applying voltage pulse of different durations to the surface of La 0.89 Sr 0.11 MnO 3 manganite single crystals and subsequently examined by the piezoresponse force microscope (PFM) technique. The domain wall velocity was then calculated based on conventional PFM procedure. A transition from the non-activated to the activated type domain wall motion has been observed due to the inhomogeneous spatial variation of the tip-induced electric field. The maximum domain size that can develop in a non-activated motion process has been found to be $170 nm. The formation of these ferroelectric-like nano domains at room temperature by PFM has been rationalized within phenomenological model based on Landau-Ginzburg formalism. Written domains are sufficiently stable and are attractive for device applications in nonvolatile random-access memories and development of metamaterials. V C 2012 American Institute of Physics. [http://dx.

show abstract

Identification of lead compounds in flames and determination of the PbO bond energy

Cited by 13 publications

References 7 publications

On the adsorption and reactivity of element 114, flerovium

On the adsorption and reactivity of element 114, flerovium

Studies on the mechanism of atom formation in graphite furnace atomic absorption spectrometry

Domain growth kinetics in La0.89Sr0.11MnO3 single crystal studied by piezoresponse force microscopy

Contact Info

Product

Resources

About