“…The interstitial atom content in this phase can reach ~24 at.% for N [12] and ~10 at.% for C [5], well above the maximum solubility of these atoms in steel composition [3]. When nitriding treatments are carried out, the formation of expanded ferrite is competitive to that of the hexagonal close-packed (hcp) ε-Fe 2-3 N nitride [11,[16][17][18][19][20], which tends to form a continuous layer, while few authors reported also the presence of γ′-Fe 4 N [17,19] and expanded austenite [21,22]. By changing the nitriding conditions it is possible to obtain a modified surface layer which consists of either expanded ferrite only [11,16], or expanded ferrite and dispersed Fe-based nitrides [16], or a continuous layer of ε-nitride on an inner layer in which expanded ferrite and nitrides are present [18].…”