We present an observational study of the vibrationally excited H 2 O line at 658 GHz ( 2 n = 1, 1 1,0 -1 0,1 ) toward Orion KL using the Atacama Large Millimeter/Submillimeter Array (ALMA). This line is clearly detected at the position of the massive protostar candidate, SourceI. The spatial structure is compact, with a size of about 100 AU, and is elongated along the northeast-southwest low-velocity (18 km −1 ) bipolar outflow traced by 22 GHz H 2 O masers, SiO masers, and thermal SiO lines. A velocity gradient can be seen perpendicular to the bipolar outflow. The overall spatial and velocity structure seems to be analogous to that of the 321 GHz H 2 O maser line previously detected with ALMA and vibrationally excited SiO maser emission. The brightness temperature of the 658 GHz H 2 O line is estimated to be higher than 2×10 4 K, implying that it is emitted via maser action. Our results suggest that the 658 GHz H 2 O maser line is emitted from the base of the outflow from a rotating and expanding accretion disk as observed for the SiO masers and the 321 GHz H 2 O maser. We also search for two other H 2 O lines at 646 GHz (9 7,3 -8 8,0 and 9 7,2 -8 8,1 ), but they are not detected in Orion KL.