(Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one

Abstract

The title compound, C22H22N2OS, exists in a cis conformation with respect to the N=C bond. The cyclo­hexene ring adopts a distorted sofa conformation. The thia­zolidine ring is essentially planar with a maximum deviation of 0.025 (2) Å and forms dihedral angles of 63.50 (7) and 57.52 (6)° with the benzene rings. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯N hydrogen bonds, generating R 2 2(8) ring motifs, and forming infinite chains along the c axis. The crystal is further consolidated by C—H⋯π inter­actions.

(Z)-3-(4-Chlorophenyl)-2-(2-phenylcyclohex-2-en-1-ylimino)thiazolidin-4-one

“…The dihedral angle between the benzene ring and chloro-substituted benzene ring is 72.91 (6)°. The bond lengths and angles are comparable to the related structures (Fun et al, 2011& Ooi et al, 2012.…”

“…For related structures, see: Fun et al (2011); Ooi et al (2012). For ring conformations, see: Cremer & Pople (1975).…”