Abstract:Key indicators: single-crystal X-ray study; T = 299 K; mean (C-C) = 0.004 Å; disorder in main residue; R factor = 0.055; wR factor = 0.156; data-to-parameter ratio = 12.0.
Primary hydroxylamines, RNHOH, decompose readily in the presence of transition metal ions. We show that this reactivity can be arrested by ligand design via an intramolecular hydrogen bond. Six metal...
Primary hydroxylamines, RNHOH, decompose readily in the presence of transition metal ions. We show that this reactivity can be arrested by ligand design via an intramolecular hydrogen bond. Six metal...
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