Abstract:The centrosymmetric title compound, [PdCl2(C19H17P)2], crystallizes with a square-planar geometry about the PdII metal centre. The most important bond distances include Pd—P (trans P) of 2.3404 (9) Å and Pd—Cl (trans Cl) of 2.2977 (12) Å. Weak intra- and intermolecular hydrogen bonding is observed in the solid-state structure between the chloro and phenyl H atoms. This weak intermolecular hydrogen-bonding pattern forms a one-dimensional chain along the b axis.
“…The molecular structure of the title compound is shown in Fig.1. The mononuclear complex is centrosymmetric, with (Ferguson et al, 1982;Meij et al, 2003;Steyl et al, 2006;Bedford et al, 2003). (Schultz et al, 1992).…”
Section: Methodsmentioning
confidence: 99%
“…For trans-dichlorido-bis[diphenyl (cyclohexyl)phosphine]palladium(II), see: Meij et al (2003). For trans-dichlorido-bis[diphenyl(p-tolyl)phosphine]palladium(II), see: Steyl et al (2006). For related literature, see: Baum et al (2006); Bedford et al (2003); Schultz et al (1992).…”
The title compound, [PdCl2(C9H21P)2], is a centrosymmetric mononuclear palladium(II) complex. The PdII atom, which lies on an inversion center, is in a square-planar geometry.
“…The molecular structure of the title compound is shown in Fig.1. The mononuclear complex is centrosymmetric, with (Ferguson et al, 1982;Meij et al, 2003;Steyl et al, 2006;Bedford et al, 2003). (Schultz et al, 1992).…”
Section: Methodsmentioning
confidence: 99%
“…For trans-dichlorido-bis[diphenyl (cyclohexyl)phosphine]palladium(II), see: Meij et al (2003). For trans-dichlorido-bis[diphenyl(p-tolyl)phosphine]palladium(II), see: Steyl et al (2006). For related literature, see: Baum et al (2006); Bedford et al (2003); Schultz et al (1992).…”
The title compound, [PdCl2(C9H21P)2], is a centrosymmetric mononuclear palladium(II) complex. The PdII atom, which lies on an inversion center, is in a square-planar geometry.
“…For the isostructural compound, trans-[PdCl 2 {P((Ph) 2 (p-Tol))} 2 ], in which the Pd centers are coordinated by Cl anions instead of Br, see: Steyl et al (2006). = 60.312 (2) V = 824.54 (6) Å 3 Z = 1 Mo K radiation = 3.11 mm À1 T = 100 K 0.33 Â 0.11 Â 0.09 mm…”
Section: Related Literaturementioning
confidence: 99%
“…The corresponding chloro complex (Steyl et al, 2006) is iso-structural to the title complex when comparing the geometrical parameters as well as the crystallization mode. The RMS error of 0.061 Å also indicate the iso-structurality of the two complexes (the title complex superimposed with the corresponding dichloro-palladium complex (Steyl et al, 2006) including the Pd, Cl(Br), P and first C atoms of the phenyl rings).…”
Key indicators: single-crystal X-ray study; T = 100 K; mean (C-C) = 0.003 Å; R factor = 0.021; wR factor = 0.051; data-to-parameter ratio = 20.3.In the title compound, [PdBr 2 (C 19 H 17 P) 2 ], the Pd II ion resides on a centre of symmetry and is coordinated by two Br anions [Pd-Br = 2.4266 (2) Å ] and two P-donor ligands [Pd-P = 2.3462 (5) Å ] in a slightly distorted square-planar geometry [P-Pd-Br = 93.528 (12) ]. Weak intermolecular C-HÁ Á ÁBr hydrogen bonds link molecules into chains extended in [110].
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