Key indicators: single-crystal X-ray study; T = 293 K; mean (C-C) = 0.004 Å; R factor = 0.034; wR factor = 0.121; data-to-parameter ratio = 14.9.In the title compound, [Ni(C 10 H 6 NO 3 ) 2 (H 2 O) 4 ], the central Ni II atom is located on an inversion center and coordinated in a slightly distorted octahedral geometry by two O atoms from two 2-oxo-1,2-dihydroquinoline-4-carboxylate ligands and four water molecules, all of which act as monodentate ligands. The crystal structure features an extensive network of intermolecular hydrogen-bonding interactions (O-HÁ Á ÁO and N-HÁ Á ÁO) and offset face-to-face -stacking interactions [centroid-centroid distances = 3.525 (3) and 3.281 (5) Å ].
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