The supersymmetric technique is applied to computing the average spectral density near zero energy in the large-N limit of the random-matrix ensembles with zero eigenvalues: B, DIII-odd, and the chiral ensembles (classes AIII, BDI, and CII). The supersymmetric calculations reproduce the existing results obtained by other methods. The effect of zero eigenvalues may be interpreted as reducing the symmetry of the zero-energy supersymmetric action by breaking a certain abelian symmetry.There exists a remarkable correspondence between large families of random-matrix ensembles and symmetric superspaces. It has been shown by Zirnbauer that in the large-N limit (N is the matrix dimension) correlation functions in random-matrix ensembles may be represented as integrals over appropriate Riemannian symmetric superspaces (with dimensions independent of N ) [1]. This relation to symmetric superspaces is based on Efetov's supersymmetric technique introducing auxiliary anticommuting (Grassmann) variables in order to directly average correlation functions over the statistical ensemble [2].At the same time, the random-matrix ensembles are known to be in one-to-one correspondence with symmetric spaces (Cartan symmetry classes) [3,4]. The classification of Zirnbauer thus establishes a correspondence between large families of symmetric spaces and Riemannian symmetric superspaces [1]. The random-matrix ensembles with zero eigenvalues were not included in the original classification, and later it became apparent that the zero eigenvalues in random-matrix ensembles are related to the reducibility of the correseponding symmetric superspaces [5,6].In this paper, I study this relation by explicitly calculating the average density of states in all random-matrix ensembles with zero eigenvalues. There are five such ensembles (Table 1): class B [so(N ) matrices at odd N ], class DIII-odd [so(2N )/u(N ) matrices at odd N ], and the three chiral ensembles: unitary AIII, orthogonal BDI, and symplectic CII. In a physical context, the ensembles B and DIII-odd appear in vortices in superconductors with odd pairing [5,7], the chiral classes -in QCD [8,9].