<i>Spin-Lattice Relaxation in Ionic Solids</i>

Manenkov, A. A.; Orbach, Raymond Lee; Hudson, R. P.

doi:10.1063/1.3034407

Cited by 21 publications

(30 citation statements)

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“…Subsequent to the early studies of relaxation of transition metal and rare earth ions in crystalline lattices, summarized in Bleaney and Stevens (1953), Manenkov and Orbach (1966), Standley and Vaughan (1969), and AI'tshuler and B. M. Kozyrev (1974), most EPR relaxation studies have been of organic radicals in fluid solution and defect centers in solids. Relaxation of metals in fluid solution and in proteins has been measured via the effect of the electron on nuclear relaxation.…”

Section: Experimental Datamentioning

confidence: 99%

Relaxation Times of Organic Radicals and Transition Metal Ions

Eaton

2002

Distance Measurements in Biological Systems by EPR

152

165

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Abstract:Review of electron spin relaxation times for organic radicals and transition metal ions in magnetically dilute samples. Emphasis is placed on studies that have been performed as a function of temperature and that provide insight into the relaxation processes. INTRODUCTION Scope of this ChapterMost of the methods for determining distances between spins (ch.l) are either experimentally feasible or theoretically applicable for a limited range of electron spin relaxation times. For example, analysis of the dipolar contribution to the CW line shape to determine interspin distance requires that the relaxation rate for the interacting partner is slow enough that the dipolar splitting is not collapsed by electron spin relaxation. In addition, analysis of the line shapes assumes that spectra are obtained under nonsaturating conditions and are free from passage effects. Application of methods based on changes in relaxation times requires that the relaxation rate of the interacting partner fall within certain limits. The longest distance that can be obtained by pulsed techniques is limited, in principle, by the relaxation-determined width of an individual spin packet. Thus, knowledge of electron spin relaxation times is foundational to the methodologies presented in this book.

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Section: Experimental Datamentioning

confidence: 99%

Relaxation Times of Organic Radicals and Transition Metal Ions

Eaton

2002

Distance Measurements in Biological Systems by EPR

152

165

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“…A large number of the most important earlier papers on spin-lattice relaxation have been reprinted together [106].…”

Section: Acoustic Attenuation For Longitudinal Waves In Hovo~mentioning

confidence: 99%

Magnetic resonance in Kazan and in Oxford

Bleaney

1992

Appl. Magn. Reson.

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“…Since then, the field has developed significantly as is, for example, outlined in the Refs. [64,65,[116][117][118][119][120][121][122][123]. In Sect.…”

Section: Non-thermalized Triplet Sublevelsmentioning

confidence: 99%

“…see the Refs. [99,[113][114][115][116][117][118][119][120][121], the almost general importance of these effects also for organometallic compounds has not yet been fully recognized. Three processes are important and govern the relaxation properties between closely lying electronic states, namely the direct, the Orbach, and the Raman process (see Refs.…”

Section: Spin Lattice Relaxation -Backgroundmentioning

confidence: 99%

Transition Metal and Rare Earth Compounds

2000

Topics in Current Chemistry

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The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use.Cover design: Friedhelm Steinen-Broo, Barcelona; MEDIO, Berlin Typesetting: Fotosatz-Service K6hler GmbH, 97084 Wiirzburg SPIN: 10719407 02/3020 ra -5 4 3 2 1 0 -Printed on acid-free paper

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Spin-Lattice Relaxation in Ionic Solids

Cited by 21 publications

References 0 publications

Relaxation Times of Organic Radicals and Transition Metal Ions

Relaxation Times of Organic Radicals and Transition Metal Ions

Magnetic resonance in Kazan and in Oxford

Transition Metal and Rare Earth Compounds

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