Abstract:Here we report a facile one‐pot regioselective synthesis of the family of chiral 1,7‐C60(CF2)(CF3)R compounds via CF2 carbene addition to in situ generated C60CF3− anion. The simplest representative of the family, C60(CF2)(CF3)Me, is unequivocally characterized and shown to feature 0.1 eV lower LUMO level than C60, that makes it a prospective electron accepting electron‐transport material.
We report synthesis and computational study of Sc3N@C78(CF2) – an analog of the previously reported Sc3N@C80(CF2) with a less common carbon cage whose chemical properties presently remain far less studied....
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