N-Phenyl-N′-(2-thienylmethylene)hydrazine

Abstract

The title mol­ecule, C11H10N2S, is almost planar with normal bond lengths and angles. The crystal packing is stabilized by C—H⋯π and van der Waals interactions.

Mono(arylhydrazino)acenaphthenones as a platform for the design of NIR chromophores based on Pd(ii)-BIAN complexes

“…53 At the same time, the C–C and N–N distances are 1.493(4) and 1.343(3) Å, respectively and are slightly shortened relative to the standard lengths of C–C and N–N single bonds. 54,55 This can be explained by the presence of ketohydrazone and azaenol tautomeric forms, which differ in bond lengths and the position of the hydrogen atom, which leads to averaging of bond lengths in the structure. 8 Molecules in a crystal packing are arranged in stacks oriented along the crystallographic c axis; the distance between molecules in the stacks is 3.6 Å.…”

Investigation of Photochemical Reactions of some Metal Carbonyls with N´-(2-Hydroxy-6- Methylbenzylidene)Methanesulfonohydrazide and 5-Methyl- 2-Hydroxyacetophenonemethanesulfonylhydrazone

“…[1][2][3][4][5] These compounds have gained importance in bioinorganic and metal based drug chemistry because of their lower cost, lower toxicity and most activity against bacterial diseases. 6,7 Moreover, they are used in agriculture field as well as insecticides and herbicides. They are less toxic as compared to other drugs and are scalable.…”

Structural, Spectroscopic and Activity Calculations on Methanesulfonylhydrazone Derivative Chromium Pentacarbonyl Complexes

“…Most compounds containing carboxylic acid hydrazones exhibit cytostatic activity. Sulfonamides (-SO2NH-) are widely used as antimicrobial agents due to their lower cost, lower toxicity and most of their activity against bacterial diseases (3). Methane sulfonamide derivatives have DNA binding ability and show cytostatic effects that are used in cancer chemotherapy.…”