N-Cyclohexyl-4-methoxybenzenesulfonamide

Abstract

In the title mol­ecule, C13H19NO3S, the S atom has a distorted tetra­hedral geometry with an O—S—O bond angle of 120.39 (18)°. The cyclo­hexane ring has a chair conformation. In the crystal, mol­ecules are connected by inter­molecular N—H⋯O hydrogen bonds, forming zigzag hydrogen-bonded chains directed along the c axis.

N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluorobenzenesulfonamide

“…The title compound, (I), (Fig. 1) was examined as part of our ongoing interest in the structural chemistry of sulfonamides (Khan et al, 2011). A number of related structures have been reported by Gelbrich et al (2007).…”

“…The C1-S1-N1-C7 linkage adopts a gauche conformation [torsion angle = -68.12 (15)°] and the bond-angle sum about N1 (H atom coordinates freely refined) is 347.2°, possibly suggesting a hybridization state intermediate between sp 2 and sp 3 . The largest bond angle at the distorted tetrahedral S atom is O1-S1-O2 [120.26 (9)°], which is typical for this class of compound (Khan et al, 2011).…”

“…For related structures, see: Khan et al (2011); Gelbrich et al (2007). independent and constrained refinement Á max = 0.24 e Å À3 Á min = À0.32 e Å À3 Table 1 Hydrogen-bond geometry (Å , ).…”

2,5-Dichloro-N-(3-methylphenyl)benzenesulfonamide

“…Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97. of sulfonamides (Khan et al, 2011;Mughal et al, 2012).…”