2023
DOI: 10.1002/admi.202202363
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N‐Butyl Pyridinium Diiodido Argentate(I): A One‐Dimensional Ag‐I Network with Superior Solid‐State Ionic Conductivity at Room Temperature

Abstract: The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Cited by 2 publications
(2 citation statements)
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“…Interestingly, the compound has a much lower melting point than the parent compound N ‐butyl pyridinium chloride and one of the lowest melting points for a metal‐containing ionic liquid structure. [ 13–20 ] The decrease in melting temperature is probably due to the anisotropic tetrahedral arrangement of the [FeCl 4 ] − moiety and due to the lack of anion‐π interactions and hydrogen bonds in the long‐range order of the material. TGA of the sample shows the compound is stable up to 250 °C without any degradation, as shown in Figure S13 (Supporting Information).…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…Interestingly, the compound has a much lower melting point than the parent compound N ‐butyl pyridinium chloride and one of the lowest melting points for a metal‐containing ionic liquid structure. [ 13–20 ] The decrease in melting temperature is probably due to the anisotropic tetrahedral arrangement of the [FeCl 4 ] − moiety and due to the lack of anion‐π interactions and hydrogen bonds in the long‐range order of the material. TGA of the sample shows the compound is stable up to 250 °C without any degradation, as shown in Figure S13 (Supporting Information).…”
Section: Resultsmentioning
confidence: 99%
“…[ 12 ] In this regard, ionic liquids based on organic–inorganic metal halides are also gaining interest in recent times due to their unique physical and chemical properties, which can be tailored by the choice of metal and ligand components. [ 13–20 ]…”
Section: Introductionmentioning
confidence: 99%