N-Benzylpropan-2-aminium (benzylisopropylamido)(2,2,2-trifluoroacetamido)phosphate

Abstract

Key indicators: single-crystal X-ray study; T = 150 K; mean (C-C) = 0.004 Å; R factor = 0.054; wR factor = 0.103; data-to-parameter ratio = 21.4.In the title compound, C 10 H 16 N + ÁC 12 H 15 F 3 N 2 O 3 P À , the two P-N distances are significantly different [1.740 (2) and 1.641 (2) Å ]. In the crystal structure, cations and anions are connected via intermolecular N-HÁ Á ÁO hydrogen bonds to form chains of centrosymmetric rings propagating in the b-axis direction. organic compounds o4318 # 2007 International Union of Crystallography

CyclohexylmethylammoniumN,N′-dicyclohexyl-N,N′-dimethyl-N′′-(2,2,2-trifluoroacetyl)phosphonic triamide)

“…Single crystal of the product [NH 2 CH 3 C 6 H 11 ][CF 3 CONPO(NCH 3 C 6 H 11 ) 2 ] was obtained from a solution of CH 3 OH -H 2 O (3:1) after a slow evaporation at room temperature. The proton transfer compound contains N-methyl cyclohexyl ammonium cation and deprotonated N′-2,2,2,-tri-flouroacetyl bis N"-methyl cyclohexyl phosphortriamide ( (Yazdanbakhsh & Sabbaghi, 2007). The phosphorus atom has slightly distorted tetrahedral configuration.…”

N-Benzylpropan-2-aminium chloride

“…In the previous works, the structure determination of [NH 2 (CH 2 C 6 H 5 )(CH (Yazdanbakhsh & Sabbaghi, 2007) have been investigated; we report here on the crystal structure of title compound, the chloride salt of N-benzyl-2-propanaminium cation ( (Fig. 2).…”