N′-(4-Chlorobenzoyl)-N-(pyrrolidin-1-yl)thiourea

Abstract

The title compound, C12H13ClN2OS, shows a twisted conform­ation with respect to the carbonyl and thio­carbonyl moieties. The crystal packing is determined by strong intermolecular N—H⋯O interactions.

The Four Faces of Competition: The Development of the Multidimensional Competitive Orientation Inventory

“…Similarly to Tassi and Schneider (1997) , some of the prior theories differentiate two main forms of competitiveness, referring to them as (a) perspectives of competitiveness ( Griffin-Pierson, 1990 ) or (b) facets of competitiveness ( Kayhan, 2003 ). In these differentiations, one of the dimensions is related to the strong desire of winning, dominating or being superior to others, while the other refers to the desire for excellence, obtaining a goal, bringing out the best one can do, mastering the task, and developing oneself.…”

“…Apart from the distinction of Griffin-Pierson (1990) and Kayhan (2003) , a different classification has also been suggested with two independent dimensions of competitiveness ( Houston et al, 2002 ; Harris and Houston, 2010 ) which differ from the above-mentioned ones based on content. The first one is enjoyment of competition which refers to personal attitudes toward one’s competitive behavior (e.g., liking, enjoying/disliking, avoiding competition), whereas the second dimension is contentiousness which refers to attitudes toward avoidant behavior in arguments and conflicts.…”

“…Therefore, measuring only one facet of competitive attitudes without considering simultaneously the other dimensions can be misleading. Besides the unidimensional measures ( Ryckman et al, 1990 , 1996 , 2009 ) there were attempts to create multidimensional ones ( Griffin-Pierson, 1990 ; Franken and Brown, 1995 ; Franken and Prpich, 1996 ; Kayhan, 2003 ; Newby and Klein, 2014 ). However, the psychometric properties of these questionnaires do not perfectly meet the most recent requirements and standards.…”

3-Nitro-N-[(pyrrolidin-1-yl)carbothioyl]benzamide

“…For standard bond-length data, see: Allen et al (1987). For related structures, see: Emen et al (2003); Kayhan et al (2003).…”

“…The rapid increase in the number of syntheses of thiourea derivatives is driven by their applications in various fields including biology, pharmacy and materials for devices. The title compound is a thiourea derivative analogue to N′-(4chlorobenzoyl)-N-(pyrrolidin-1-yl)thiourea (Kayhan et al, 2003) and N′-(2-chlorobenzoyl)-N-(pyrrolidin-1-yl) (Emen et al, 2003), except for the nitro substituent attached at 3-position of the benzene ring (Fig. 1).…”