<i>N</i>-(2-Naphthyloxymethylcarbonyl)pyrrolidine

Thamotharan, Subbiah; Parthasarathi, V.; Gupta, Prabhat K.; Jindal, D. P.; Piplani, Poonam; Linden, Anthony

doi:10.1107/s1600536803017987

Cited by 12 publications

(12 citation statements)

References 8 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…One methyl group of the dimethylsubstituted N atom appears to be disordered over two sites with the major conformation occurring in approximately 67% of the molecules. The bond lengths and angles in (I) are comparable with those in the related structures N-(2naphthyloxymethylcarbonyl)piperidine and 3-methyl-N-(2naphthyloxymethylcarbonyl)piperidine (Thamotharan et al, 2003), as well as 4-(2-naphthyloxymethylcarbonyl)morpholine and 1-(2-naphthyloxymethylcarbonyl)-4-methylpiperazine (Thamotharan et al, 2003a). In (I), the C2ÐO11ÐC12ÐC13 [178.56 (16) ] and O11ÐC12ÐC13ÐN14 [179.19 (18) ] torsion angles show that the central unit has an antiperiplanar conformation.…”

Section: Commentsupporting

confidence: 64%

N,N-Dimethyl-2-(2-naphthyloxy)acetamide monohydrate

et al. 2003

Self Cite

View full text Add to dashboard Cite

The title compound, C14H15NO2·H2O, is a potential antiamnesic agent. One methyl group of the dimethyl‐substituted N atom appears to be disordered over two sites. In the crystal structure, the water molecule is involved in intermolecular hydrogen bonds with two neighbouring water molecules, as well as with the O atom of the amide group. The water⋯water interactions form extended chains which run parallel to the c axis. Intermolecular C—H⋯O and C—H⋯π interactions are also observed.

show abstract

Section: Commentsupporting

confidence: 64%

N,N-Dimethyl-2-(2-naphthyloxy)acetamide monohydrate

et al. 2003

Self Cite

View full text Add to dashboard Cite

show abstract

“…As given in Fig. 3 and Table 1, the distance between CB3 and F4, HB3 and F4 are 3.276 and 2.36 Å , respectively, being consistent with C-HÁ Á ÁF hydrogen bonds (3.455 and 2.53 Å , respectively; Thamotharan et al, 2003). The packing pattern of the title compound is shown in Fig.…”

supporting

confidence: 72%

[5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinato]zinc(II) benzene disolvate

Lin

2020

IUCr Data

View full text Add to dashboard Cite

Single crystals of the title zinc porphyrinato complex, [Zn(C44H8F20N4)]·2C6H6, were obtained by the solvent evaporation method. The molecular complex exhibits point group symmetry \overline1 with the central ZnII atom located on an inversion centre. The porphyrinato core is approximately planar, and the cation has no other ligating atoms than the four porphyrinato N atoms. π–π interactions between benzene solvent molecules and [Zn(TFPP)] units lead to multilayer packing structures. In addition, intermolecular C—H...F hydrogen bonding is observed between [Zn(TFPP)] molecules.

show abstract

“…The present study is part of an ongoing investigation of the crystal structures of a series of androstene derivatives (Thamotharan et al, 2002(Thamotharan et al, , 2004Hema et al, 2003). We are particularly interested in studying the conformational¯exibilities of the steroid nucleus resulting from various substitutions at the C3, C16 and C17 positions.…”

Section: Commentmentioning

confidence: 99%

16-(4-Isopropylbenzylidene)androst-4-ene-3,17-dione

et al. 2004

Self Cite

View full text Add to dashboard Cite

In the title compound, C(29)H(36)O(2), the outer cyclohexene ring of the steroid nucleus has a conformation that lies about half-way between a half-chair and an envelope, while the central and outer cyclohexane rings of the steroid nucleus have slightly distorted chair conformations. The steroidal cyclopentane ring adopts a 13beta,14alpha-half-chair conformation. The benzylidene moiety has an E configuration with respect to the carbonyl group on the cyclopentane ring. The dihedral angle between the mean planes of the steroid nucleus and the benzylidene moiety is 35.54 (9) degrees. The packing of the molecules is assumed to be dictated mainly by weak intermolecular C-H.O interactions.

show abstract

N-(2-Naphthyloxymethylcarbonyl)pyrrolidine

Cited by 12 publications

References 8 publications

N,N-Dimethyl-2-(2-naphthyloxy)acetamide monohydrate

N,N-Dimethyl-2-(2-naphthyloxy)acetamide monohydrate

[5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinato]zinc(II) benzene disolvate

16-(4-Isopropylbenzylidene)androst-4-ene-3,17-dione

Contact Info

Product

Resources

About