[N-(2-Aminocyclohexyl)salicylaldiminato-κ³O,N,N′]dichlorophenyltin(IV) chloroform solvate

Abstract

Key indicatorsSingle-crystal X-ray study T = 223 K Mean '(C±C) = 0.007 A Ê R factor = 0.041 wR factor = 0.114 Data-to-parameter ratio = 21.4For details of how these key indicators were automatically derived from the article, see

trans-Dichloridobis(dimethyl sulfoxide-κO)bis(4-fluorobenzyl-κC 1)tin(IV): crystal structure and Hirshfeld surface analysis

“…In view of this, the coordination of these multidentate ligands to (organo)tin may lead to more thermodynamically stable organotin complexes, in contrast to those with monodentate ligands (Vallet et al, 2003;Contreras et al, 2009), a feature which could potentially be useful in catalytic studies (Yearwood et al, 2002). In consideration of this and as part of ongoing work with multidentate ligands of organotin compounds (Lee et al, 2004), an attempt to synthesize an adduct of the potentially tetradentate Schiff base N,N-1,1,2,2-dinitrilevinylenebis(5-bromosalicylaldiminato) with di(p-fluorobenzyl)tin(IV) dichloride was made.…”

Heterodinuclear Ni(II)—Sn(II) complexes from reduced ONNO type Schiff base compounds

“…[7][8][9]. Studies about tin Schiff base complexes are very little and most of them report in its 4þ (Sn) form [10][11][12][13].…”