<i>N</i>-(2,3-Dimethylphenyl)-4-fluoro-<i>N</i>-[(4-fluorophenyl)sulfonyl]benzenesulfonamide

Key indicators: single-crystal X-ray study; T = 296 K; mean (C-C) = 0.005 Å; R factor = 0.055; wR factor = 0.129; data-to-parameter ratio = 17.2.In the title compound, C 22 H 23 NO 4 S 2 , the dihedral angles between the dimethylphenyl ring and the two methylphenyl rings are 41.19 (15) and 20.50 (17) ; the dihedral angle between the methylphenyl rings is 48.11 (14) . The C-N-S-C torsion angles are À87.6 (2) and 77. 43 (18) . The only possible directional interactions in the crystal are very weak C-HÁ Á Á interactions and very weak -stacking between parallel methylphenyl rings [centroid-to-centroid separation = 4.010 (2) Å and slippage = 1.987 Å ]. Related literature

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N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide

Mughal

Khan

Harrison

et al. 2012

Acta Cryst E

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Crystal structure and Hirshfeld surface analysis of N-[2-(5-methylfuran-2-yl)phenyl]-3-nitro-N-[(3-nitrophenyl)sulfonyl]benzenesulfonamide

Mammadova,

Annadurdyyeva,

Burkin

et al. 2023

Acta Cryst E

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In the title compound, C23H17N3O9S2, C—H...O hydrogen bonds link adjacent molecules in a three-dimensional network, while π–π stacking interactions, with centroid–centroid distances of 3.8745 (9) Å, between the furan and an arene ring of one of the two (3-nitrophenyl)sulfonyl groups, result in chains parallel to the a axis. The Hirshfeld surface analysis indicates that O...H/H...O (40.1%), H...H (27.5%) and C...H/H...C (12.4%) interactions are the most significant contributors to the crystal packing.

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Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide

Mammadova,

Yakovleva,

Burkin

et al. 2023

Acta Cryst E

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In the title compound, C25H17N3O5S2, intramolecular π–π interactions [centroid-to-centroid distance = 3.5640 (9) Å] are observed between the furan and benzene rings of the 4-cyanophenyl group. In the crystal, molecules are connected via C—H...O and C—H...N hydrogen bonds, forming layers parallel to the (100) plane. These layers are interconnected by C—H...π interactions and weak van der Waals interactions. Hirshfeld surface analysis indicates that H...H (30.2%), N...H/H...N (22.3%), C...H/H...C (17.9%) and O...H/H...O (15.4%) interactions make the most significant contributions to the crystal packing.

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N-(2,3-Dimethylphenyl)-4-fluoro-N-[(4-fluorophenyl)sulfonyl]benzenesulfonamide

Cited by 3 publications

References 5 publications

N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide

N-(2,3-Dimethylphenyl)-4-methyl-N-(4-methylphenylsulfonyl)benzenesulfonamide

Crystal structure and Hirshfeld surface analysis of N-[2-(5-methylfuran-2-yl)phenyl]-3-nitro-N-[(3-nitrophenyl)sulfonyl]benzenesulfonamide

Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyanophenyl)sulfonyl]-N-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide

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