meso-Halogenated nitrosylcobalamins: Formation and aerobic stability
Ilia A. Dereven’kov,
Vladimir S. Osokin,
Nikita A. Ershov
et al.
Abstract:Here, we report the results of the investigation of reactions between brominated and chlorinated at the C10 position of corrin cyano- (CNCbl-Hal, Hal = Br, Cl) and aquacobalamins (H2OCbl-Hal) and Angeli’s salt (AS). The reactions involving H2OCbl-Hal and AS proceed via two parallel routes, i.e., reactions between H2OCbl-Hal or HOCbl-Hal and HNO generated upon decomposition of AS and between H2OCbl-Hal and AS, and generate corresponding nitrosylcobalamins (NOCbl-Hal). In contrast to the process involving unmodi… Show more
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