Theoretical calculations of the shape of an absorption edge in a warm dense simple
material such Al are described. The calculations include the XAFS (x-ray absorption fine
structure) features above the edge. The shape of these modulations relates to the atomic
spatial distribution and to the electronic density of states (DOS) in the continuum. The
underlying warm dense plasma model is based on a density-functional neutral
pseudoatom approach which gives the radial distribution function (RDF) and the
electron density around one specific site. Combined with a full multiple-scattering
(MS) approach giving the final free wavefunction in a photoionization process, the
model is used to predict the shape of photoabsorption K edges over a range of
compression ratios from 0.5 to 3 and temperatures from 0.1 to 10 eV. It is found that
XAFS structures are intense enough to be observable for densities of the order of
(and above) the solid density and that dynamic or static absorption spectroscopy
measurements could provide interesting information on the warm dense matter
regime.