<i>fac</i>-Dichlorotris(trimethylphosphine)(trimethylphosphoniomethyl)rhodium(III) chloride/bromide dichloromethane benzene solvate

Batsanov, Andrei S.; Marder, Todd B.; Seeler, Fabian

doi:10.1107/s1600536806005630

Acta Cryst E

2006

DOI: 10.1107/s1600536806005630

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fac-Dichlorotris(trimethylphosphine)(trimethylphosphoniomethyl)rhodium(III) chloride/bromide dichloromethane benzene solvate

Andrei S. Batsanov¹,

Todd B. Marder²,

Fabian Seeler³

Abstract: The title complex, [RhCl2(C4H11P)(C3H9P)3](Br0.12/Cl0.88)·CH2Cl2·C6H6, has an ionic structure with fac‐octahedral coordination of RhIII in the cation. The anion is a mixture of Cl and Br in a 7:1 ratio.

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fac-Dichlorotris(trimethylphosphine)(trimethylphosphoniomethyl)rhodium(III) chloride/bromide dichloromethane benzene solvate

Abstract: The title complex, [RhCl2(C4H11P)(C3H9P)3](Br0.12/Cl0.88)·CH2Cl2·C6H6, has an ionic structure with fac‐octahedral coordination of RhIII in the cation. The anion is a mixture of Cl and Br in a 7:1 ratio.

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References 8 publications

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fac-Dichlorotris(trimethylphosphine)(trimethylphosphoniomethyl)rhodium(III) chloride/bromide dichloromethane benzene solvate

Abstract: The title complex, [RhCl2(C4H11P)(C3H9P)3](Br0.12/Cl0.88)·CH2Cl2·C6H6, has an ionic structure with fac‐octa­hedral coordination of RhIII in the cation. The anion is a mixture of Cl and Br in a 7:1 ratio.

Cited by 0 publications

References 8 publications

No citations

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Product

Resources

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Abstract: The title complex, [RhCl2(C4H11P)(C3H9P)3](Br0.12/Cl0.88)·CH2Cl2·C6H6, has an ionic structure with fac‐octahedral coordination of RhIII in the cation. The anion is a mixture of Cl and Br in a 7:1 ratio.