I. Ethyl Trichlorosilane and its Fluorination Products<sup>1</sup>

Booth, Harold Simmons; Carnell, Paul H.

doi:10.1021/ja01216a069

Cited by 17 publications

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“…A data base consisting of critical temperature and pressure data was employed to regress silicon contribution values for use with the prediction methods developed by Lyderson (15) and Ambrose (16,17). For critical temperature, 5 silicon contribution values for each method were determined from the experimental data of 45 compounds.…”

Section: Critical Propertiesmentioning

confidence: 99%

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Prediction of properties of silicon, boron, and aluminum compounds

Myers¹,

Danner²

1993

J. Chem. Eng. Data

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Section: Critical Propertiesmentioning

confidence: 99%

“…new silicon group contributions, i v i d u a l n o t d i r e c t l y a s s o c i a t e d w i t h s c i t e i s p r o h i b i t e d .TableII. Bond Contributions for the Prediction of the Enthalpy of Formation ( 0^) at 298 15. An asterisk indicates a group determined by a single compound.…”

mentioning

confidence: 99%

Prediction of properties of silicon, boron, and aluminum compounds

Myers¹,

Danner²

1993

J. Chem. Eng. Data

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Swarts Reaction

2010

Comprehensive Organic Name Reactions and Reagents

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The partial fluorination of nonpolar organic polyhalides (mostly aliphatic) with antimony trifluoride in the presence of antimony pentachloride or chlorine is generally referred to as the Swarts reaction and the mixture of antimony trifluoride and chlorine (SbF 3 + Cl 2 ) is known as the Swarts reagent. It has been reported that only aryl halides carrying more than one electron‐withdrawing group (e.g., NO 2 ) on the aromatic ring can react with fluoride. Furthermore, this reaction is not likely to take place under the reduced pressure. After fluorination, it has been found that the resulting fluoride has a lower boiling point than the corresponding chloride and this phenomenon is known as the Swarts rule. This reaction has been modified by the addition of fluorine, halogen fluoride, fluorides of noble gases and is useful for the preparation of organic fluorides.

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Über Fluorchemie. VI. Der Einfluß von Bortrifluorid auf Antimontrifluorid als Fluorierungsmittel in der Kohlenstoff‐ und in der Siliciumchemie

Müller

Dathe

1961

J. Prakt. Chem.

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Antimontrifluorid fluoriert gewisse geminale und trigeminale, nicht aber monotope CCl‐Bindungen. Dagegen werden alle (auch monotope) SiCl‐Bindungen davon fluoriert. Zusatz von fünfwertigem Antimon ist zu deren Fluorierung unnötig. Fluorierungen trigeminaler CCl‐ werden durch Bortrifluorid beschleunigt, die der SiCl‐Bindungen gehemmt. In Anlehnung an die Fluorierungstheorie von BOOTH wird vermutet, daß die Fluorierung der SiCl‐Bindungen vom einsamen Elektronenpaar am Antimon eingeleitet wird.

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I. Ethyl Trichlorosilane and its Fluorination Products¹

Cited by 17 publications

References 0 publications

Prediction of properties of silicon, boron, and aluminum compounds

Prediction of properties of silicon, boron, and aluminum compounds

Swarts Reaction

Über Fluorchemie. VI. Der Einfluß von Bortrifluorid auf Antimontrifluorid als Fluorierungsmittel in der Kohlenstoff‐ und in der Siliciumchemie

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I. Ethyl Trichlorosilane and its Fluorination Products1

Cited by 17 publications

References 0 publications

Prediction of properties of silicon, boron, and aluminum compounds

Prediction of properties of silicon, boron, and aluminum compounds

Swarts Reaction

Über Fluorchemie. VI. Der Einfluß von Bortrifluorid auf Antimontrifluorid als Fluorierungsmittel in der Kohlenstoff‐ und in der Siliciumchemie

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I. Ethyl Trichlorosilane and its Fluorination Products¹