<i>E/Z</i>‐Isomerisierung in Kristallen – Phasenumbildung bei der Photolyse mit langwelliger Strahlung

Kaupp, Gerd; Haak, Michael

doi:10.1002/ange.19961082309

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Synthetic Routes To and Chemical Compositions Of Tpp⋅x′(thf)1

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Cited by 4 publications

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“…However, such a mechanism would involve the channel wall showing some flexibility. A mechanism for solid‐state reactions in molecular crystals was recently proposed, which assumed considerable flexibility of molecular lattices 16…”

Section: Synthetic Routes To and Chemical Compositions Of Tpp⋅x′(thf)mentioning

confidence: 99%

Supramolecular-Wire Confinement of I2 Molecules in Channels of the Organic Zeolite Tris(o-phenylenedioxy)cyclotriphosphazene

Hertzsch

Budde

Weber

et al. 2002

Angew. Chem. Int. Ed.

139

106

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Efficient guest exchange: The organic zeolite analogue TPP⋅x(THF) (x=0.35–0.65) takes up I2 quickly when exposed to iodine vapor. The previously colorless crystals (a) color at the ends (b), and after 1–2 days the iodine has permeated all the way through the crystal (c). The conductivity values of the TPP⋅y(I2) crystals are of the same order as those of elemental I2. TPP=tris(o‐phenylenedioxy)cyclotriphosphazene.

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Section: Synthetic Routes To and Chemical Compositions Of Tpp⋅x′(thf)mentioning

confidence: 99%

Supramolecular-Wire Confinement of I2 Molecules in Channels of the Organic Zeolite Tris(o-phenylenedioxy)cyclotriphosphazene

Hertzsch

Budde

Weber

et al. 2002

Angew. Chem. Int. Ed.

139

106

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Tris(o-phenylendioxy)cyclotriphosphazen mit eingeschlossenen Iodmolekülen: ein supramolekularer elektrischer Leiter

et al. 2002

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Solvent-Free Routes to Clean Technology

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A major aim for the chemical technology of the future is the avoidance of noxious and environmentally unacceptable organic solvents. In this concept article we discuss more environmentally friendly and highly selective alternatives which we have evolved for carrying out a number of important chemical conversions. These entail the use of porous heterogeneous catalysts in which the active sites have been atomically engineered and fully characterized. Such solid catalysts operate under solvent-free conditions and usually entail one-step processes.

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E/Z‐Isomerisierung in Kristallen – Phasenumbildung bei der Photolyse mit langwelliger Strahlung

Cited by 4 publications

References 19 publications

Supramolecular-Wire Confinement of I2 Molecules in Channels of the Organic Zeolite Tris(o-phenylenedioxy)cyclotriphosphazene

Supramolecular-Wire Confinement of I2 Molecules in Channels of the Organic Zeolite Tris(o-phenylenedioxy)cyclotriphosphazene

Tris(o-phenylendioxy)cyclotriphosphazen mit eingeschlossenen Iodmolekülen: ein supramolekularer elektrischer Leiter

Solvent-Free Routes to Clean Technology

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