Dodonaea angustifolia Extract-Assisted Green Synthesis of the Cu₂O/Al₂O₃ Nanocomposite for Adsorption of Cd(II) from Water

Abstract

The enhanced worldwide concern for the protection and safety of the environment has made the scientific community focus their devotion on novel and highly effective approaches to heavy metals such as cadmium (Cd) pollutant removal. In this research, Dodonaea angustifolia plant extract-mediated Al 2 O 3 and Cu 2 O nanoparticle (NP) syntheses were accomplished using the coprecipitation method, and the Cu 2 O/Al 2 O 3 nanocomposite was prepared by simple mixing of Cu 2 O and Al 2 O 3 NPs for the removal of Cd(II) ions from aqueous solution. Therefore, an efficient green, economical, facile, and eco-friendly synthesis method was employed, which improved the aggregation of individual metal oxide NPs. The chemical and physical properties of the nanocomposite were examined by different characterization techniques, including scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and Brunauer−Emmett−Teller (BET) surface area analysis. Furthermore, the performances of the nanoadsorbents for the adsorptive eradication of Cd 2+ ions from water were investigated. The influence of pH, contact time, initial Cd quantity, and nanocomposite amount on adsorption effectiveness was carefully studied. The adsorption rates of the Cu 2 O/Al 2 O 3 nanocomposite were rapid, and adsorption equilibrium was attained within 60 min for 97.36% removal of Cd(II) from water. The adsorption isotherm data were best fitted by the pseudo-second-order kinetic and Langmuir isotherm models with the highest adsorption ability of 4.48 mg/g. Therefore, the synthesized Cu 2 O/Al 2 O 3 nanocomposite could be a potential candidate for a highly efficient adsorbent for heavy metal ion removal from aqueous solutions.

Hagenia abyssinica-Biomediated Synthesis of a Magnetic Fe3O4/NiO Nanoadsorbent for Adsorption of Lead from Wastewater

“…One of the highly effective and straightforward strategies for eliminating heavy metal ions is adsorption technology, which is dependent on cutting-edge adsorbent materials . For heavy metal removal, various adsorbents were used, including activated carbons, carbon nanotubes, and natural inorganic mineral-functionalized polymers and porous materials. − The main drawback of all of the previous adsorbents was that they were difficult to separate and regenerate from wastewater. Consequently, novel adsorbents with remarkable adsorption ability and facile separation of heavy metals from a large quantity of water remain in demand.…”