Crystal structures of (Et₄N)₂C₂S₆, (Et₄N)₂C₂S₅, (Et₄N)₂CS₄, (Et₄N)HCS₃, (Et₄N)₂CS₃ ⋅ 2H₂O and (Et₄N)₂CS_4‐y ⋅ yH₂O (y=0.69).

Abstract

The crystal structures of (Et 4 N) 2 C 2 S 6 , (Et 4 N) 2 C 2 S 5 , (Et 4 N) 2 CS 4 , (Et 4 N) HCS 3 , (Et 4 N) 2 CS 3 • 2H 2 O and (Et 4 N) 2 CS 4-y • yH 2 O (y = 0.69) were determined by single-crystal X-ray diffraction analysis at 150 K. For the first time, salts with the C 2 S 5 2À and HCS 3 À anions could be synthesized.