cis ‐Cyclohexan‐diol aus Cyclohexen‐oxyd

Mechanisms Of Epoxide Reactions

“…Thus the reaction of ammonia with trans-2,3-epoxybutane might give either erythro-or </ireo-3-amino-2-butanol: only the erythro isomer is produced(62), corresponding to inversion of configuration at the point of attack. Similarly, the acid-catalyzed hydration of cyclohexene oxide gives only iraros-cyclohexane-1,2-diol, none of the cis isomer being formed(21,52).OH T h i s c o n t e n t i s o n l y l i c e n s e d f o r c o n s u m p t i o n b y A u t h o r i z e d U s e r s a f f i l i a t e i n d i v i d u a l n o t d i r e c t l y a s s o c i a t e d w i t h s c i t e i s p r o h i b i t e d .…”