Bis(Diethyldithiocarbamato)Antimony(III) Derivatives with Oxygen- and Sulfur-Donor Ligands: Synthesis, Esi-Mass, and Spectral Characterization

Preparation, spectroscopic, thermal and powder X‐ray diffraction characterization, and antimicrobial activities of mixed bis(O,O′‐diisopropyldithiophosphato‐S,S′)antimony(III) derivatives with some oxygen and sulfur donor ligands

“…The 13 C NMR spectra of all the derivatives have been assigned on the basis of previous reports and the data are summarized in Table . The proton decoupled 13 C NMR spectra of the bis( O , O ′‐diisopropyldithiophosphato‐ S , S ′)antimony(III) derivatives exhibited two signals, one at 22.21–23.76 ppm due to carbon atoms of gem C H 3 group and another at 72.12–74.21 ppm as a doublet due to PO C H carbon resonances.…”

Syntheses, characterization, antibacterial activity and molecular modelling of phenylantimony(III) heteroleptic derivatives containing substituted oximes and piperidine dithiocarbamate

“…Phenylantimony(III) dichloride, sodium salt of piperidine dithiocarbamate and substituted oximes ( 1a – 1f ) were synthesised using literature methods. Antimony was estimated iodometrically and molecular weights of derivatives were determined cryoscopically using camphor as solvent, by the Rast method. All reactions were carried out under anhydrous conditions.…”

“…In addition, dithiocarbamate derivatives with various metals have also been extensively studied because of their biological activities and use in analytical chemistry and as medicines as antidotes and antioxidants . Survey of the literature reveals that derivatives containing Sb─S bonds have also been widely used in industrial processes …”

Mixed bis(morpholine‐4‐dithiocarbamato‐S,S′)antimony(III) complexes: synthesis, characterization and biological studies

“…In continuation of our studies, [26,27a–d] we report herein the synthesis of mixed bis(morpholine‐4‐dithiocarbamato‐ S , S ′)antimony(III) complexes with oxygen or sulfur donor ligands and their characterization by spectral techniques. The complexes upon thermal decomposition in inert nitrogen atmosphere give antimony sulfide (Sb 2 S 3 ) as the last degradation product.…”

“…Apart from dithiocarbamates, other interesting families of ligands are carboxylates [24a,b,25a] and thiocarboxylates [25a,b] . The synthesis and structural characterization of antimony(III) dithiocarbamato complexes with carboxylic or thiocarboxylic group‐containing ligands have been reported recently in our laboratory …”