Hypersensitive ratiometric temperature sensing in a bimetallic lanthanide metal–organic framework

Abstract

Ratiometric luminescent temperature sensing based on a single matrix is highly desirable at current. However, the adjustments of temperature response range and sensitivity are still a huge challenge. Herein, a...

Linker installation transformations in a 2-D rare earth MOF: increase of the dimensionality and turn on of the temperature sensing capability

“…The advantages of using RE-MOFs as thermometers include their high sensitivity, reversible response, and potential for remote sensing using luminescence signals. 42 Despite the fact that there are quite a few mixed metal RE 3+ MOFs, mainly Eu–Tb ones, that have been studied as temperature sensors 43–45 the list of hexanuclear (RE 3+ ) 6 MOFs investigated as photoluminescence thermometers is quite limited. 46,47 In addition, there are very few studies investigating the fine tuning of the thermometry properties of MOFs through SCSC transformations.…”