Hydroxyl radical-related electrogenerated chemiluminescence reaction for a ruthenium tris(2,2′)bipyridyl/co-reactants system at boron-doped diamond electrodes

Boron-doped diamond electrodes in organic media: Electrochemical activation and selectivity effects

“…Applications of boron-doped diamond electrodes have been proposed in anodic waste degradation [6] and decoloration [7], hydroxyl radical [8] and ozone [9] generation, production of peroxophosphates [10] and peroxocarbonates [11], analytical sensing [12][13][14][15][16][17], in bio-sensors [18], but also electro-organic synthesis [19][20][21]. The use and benefits of boron-doped diamond electrodes in organic solvent systems was proposed first by Fujishima et al [22] and later work was expanded to include both anodic [23] and cathodic processes [24].…”

Electrochemical Detection of Sugar-related Compounds Using Boron-doped Diamond Electrodes

“…37 Moreover, this hydroxy radical is used for the combustion of organic compounds. 38,39 Therefore, hydroxy radicals are also expected to be generated on the surface of the BDD electrode in the present study; hydroxy radicals are generated by the electrolysis of water, and then indirectly oxidize glucose according to the following two-step mechanism:…”

“…The BDD electrode surface allows the production of hydroxy radicals from the electrolysis of water. [36][37][38][39] Experimental evidence has been provided for the generation of hydroxyl radicals on BDD electrodes using coumarin, followed by fluorescence detection of the hydroxylation product. 37 Moreover, this hydroxy radical is used for the combustion of organic compounds.…”

Characterization of boron doped diamond during oxidation processes: Relationship between electronic structure and electrochemical activity

“…Wide-ranging work has been carried out by several research groups, such as those of Swain [1][2][3][4][5], Fujishima [6][7][8][9][10][11][12], Comninellis [12][13][14][15] and Pleskov [16][17][18][19], just to cite some of their more recent papers. Some scientific journals and several congresses have been specifically devoted to the presentation of results obtained, both in basic studies and for possible applications of this material in electroanalytical devices and electrochemical processes [20][21][22][23][24].…”