Hydrothermal Synthesis, Crystal Structure and Electrochemical Property of Two Inorganic–Organic Hybrid Frameworks via Hydrogen Bonding

Ding, Yu; Fu, Zhengbing; X, Hu; Xia, Cai-Fen

doi:10.1007/s10904-010-9387-0

Cited by 7 publications

(2 citation statements)

References 23 publications

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“…This peak can be attributed to FeL 2 À complexes that form predominantly under these conditions. 21,22 Under excess metal conditions, the peak gradually disappears, while a new peak appears around 350 nm, which is ascribed to the formation of FeL + complexes, as can be seen from Figure 1b. We conclude from this that the absorbance peak at 370 nm can be used to identify the presence of FeL 2 À complexes.…”

Section: ' Results and Discussionmentioning

confidence: 70%

Effect of pH on Complex Coacervate Core Micelles from Fe(III)-Based Coordination Polymer

et al. 2011

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The effect of pH on iron-containing complex coacervate core micelles [Fe(III)-C3Ms] is investigated in this paper. The Fe(III)-C3Ms are formed by mixing cationic poly(N-methyl-2-vinylpyridinium iodide)-b-poly(ethylene oxide) [P2MVP(41)-b-PEO(205)] and anionic iron coordination polymers [Fe(III)-L(2)EO(4)] at stoichiometric charge ratio. Light scattering and Cryo-TEM have been performed to study the variations of hydrodynamic radius and core structure with changing pH. The hydrodynamic radius of Fe(III)-C3Ms is determined mainly by the corona and does not change very much in a broad pH range. However, Cryo-TEM pictures and magnetic relaxation measurements indicate that the structure of the micellar cores changes upon changing the pH, with a more crystalline, elongated shape and lower relaxivity at high pH. We attribute this to the formation of mixed iron complexes in the core, involving both the bis-ligand and hydroxide ions. These complexes are stabilized toward precipitation by the diblock copolymer.

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Section: ' Results and Discussionmentioning

confidence: 70%

Effect of pH on Complex Coacervate Core Micelles from Fe(III)-Based Coordination Polymer

et al. 2011

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“…A strong peak appeared at 586 cm −1 , corresponding to the vibration modes of all spinel compounds, which is attributed to the M-O stretching bands in tetrahedral complexes. [43][44][45][46] The absorption broad band at 3433 cm −1 represents the stretching mode of H 2 O molecules and OH groups. The band around 1627 cm −1 corresponds to the bending mode of H 2 O molecules [47] (Figs.…”

Section: Resultsmentioning

confidence: 99%

Magnetically separable nano CuFe₂O₄: an efﬁcient and reusable heterogeneous catalyst for the green synthesis of thiiranes from epoxides with thiourea

Eisavi

Ghadernejad

Zeynizadeh

et al. 2016

Journal of Sulfur Chemistry

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Synthesis, Characterizations and Luminescent Properties of Two Cadmium(II) Coordination Polymers Derived from Bis(Benzimidazole)-Based Ligands

Xiao

et al. 2013

J Inorg Organomet Polym

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Hydrothermal Synthesis, Crystal Structure and Electrochemical Property of Two Inorganic–Organic Hybrid Frameworks via Hydrogen Bonding

Cited by 7 publications

References 23 publications

Effect of pH on Complex Coacervate Core Micelles from Fe(III)-Based Coordination Polymer

Effect of pH on Complex Coacervate Core Micelles from Fe(III)-Based Coordination Polymer

Magnetically separable nano CuFe₂O₄: an efﬁcient and reusable heterogeneous catalyst for the green synthesis of thiiranes from epoxides with thiourea

Synthesis, Characterizations and Luminescent Properties of Two Cadmium(II) Coordination Polymers Derived from Bis(Benzimidazole)-Based Ligands

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Hydrothermal Synthesis, Crystal Structure and Electrochemical Property of Two Inorganic–Organic Hybrid Frameworks via Hydrogen Bonding

Cited by 7 publications

References 23 publications

Effect of pH on Complex Coacervate Core Micelles from Fe(III)-Based Coordination Polymer

Effect of pH on Complex Coacervate Core Micelles from Fe(III)-Based Coordination Polymer

Magnetically separable nano CuFe2O4: an efﬁcient and reusable heterogeneous catalyst for the green synthesis of thiiranes from epoxides with thiourea

Synthesis, Characterizations and Luminescent Properties of Two Cadmium(II) Coordination Polymers Derived from Bis(Benzimidazole)-Based Ligands

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Magnetically separable nano CuFe₂O₄: an efﬁcient and reusable heterogeneous catalyst for the green synthesis of thiiranes from epoxides with thiourea